Potential energy curves and vibration-rotation energies for the two purely long-range bound states 1u and 0g− of the alkali dimers M2 dissociating to M(ns2S12) + M(np2P32) with M = Na, K, Rb, and Cs
作者： B. Bussery , M. Aubert-Frécon
DOI: 10.1016/0022-2852(85)90115-8
关键词: Alkali metal 、 Inorganic compound 、 Dimer 、 Range (particle radiation) 、 Physics 、 Diatomic molecule 、 Rotation 、 Potential energy 、 Atomic physics 、 Bound state
摘要: Abstract The potential energy curves and the vibration-rotation energies have been calculated in approximation of multipolar expansion interatomic including or not second-order terms for two purely long-range bound states 1 u 0 g − alkali dimers dissociating to M (ns 2 S ) + (np P 3 = Na, K, Rb, Cs. Results good agreement with previous ones are obtained when considering only first-order terms, influence is discussed.
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