Hybrid transitions in sodium dimers by laser absorption spectroscopy

摘要: Abstract This paper reports the laser absorption transition from molecular bound state X1Σ+g of Na2 to repulsive hump otherwise B 1Πu. The photodissociation 1Πu results in production 3 2 P 1/2,3/2 atomic sodium. A photon same pulse causes an Na (6S) state. excited Rydberg atom, on collision with other atoms, ionizes produce ion-current ionization cell, which is subsequently processed by a box-car integrator and plotted chart recorder as function tunable dye energy. Such hybrid transitions simultaneously involving states within have been observed for metals, Rb or Cs, but are first time being reported here present work establishes correlation dimer both terms ( J = ) doublet .