A simple empirical model for the collisional spectral shift of air-broadened CO2 lines

作者: J.-M. Hartmann

DOI: 10.1016/J.JQSRT.2009.05.016

关键词: Spectral shiftQuantum numberSimple (abstract algebra)Complement (set theory)Co2 absorptionComputational physicsAntisymmetric relationPhysics

摘要: Abstract A simple empirical model is proposed for the pressure-induced shifts of air-broadened CO2 absorption lines. It based on introduction components symmetric and antisymmetric with respect to rotational quantum number m, a separation vibrational contributions. These are modelled though analytical laws parameters that obtained from fits measured in only two different bands. then shown leads satisfactory results other transitions which take significantly values. This provides way generate values unmeasured this tool can thus be used complement spectroscopic databases.

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