Internal solvation effects on the conformation of acyclics
作者： R.A. Auerbach , C.A. Kingsbury
DOI: 10.1016/S0040-4020(01)91604-7
关键词: Solvent 、 Solvation 、 Chemistry 、 Inorganic chemistry 、 Computational chemistry 、 Aqueous solution 、 Solvation shell 、 Methanol 、 Implicit solvation 、 Coupling constant
摘要: Abstract Experiments attempting to discern internal solvation (or H—bonding) of COOH or COO− by OH are outlined. In aqueous solutions little evidence for exists. basic methanol this effect appears due poor the solvent. The origin anomalous coupling constants in t-butyl compounds is discussed briefly.
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