A Gadolinium‐Bridged Polytungstoarsenate(III) Nanocluster: [Gd8As12W124O432(H2O)22]60−

作者: Firasat Hussain , Franziska Conrad , Greta���R. Patzke

DOI: 10.1002/ANIE.200903299

关键词: Atomic force microscopyNanotechnologyLibrary scienceMagnetic measurements

摘要: This work was supported by the Swiss National Science Foundation (SNSF Professorship PP002-114711/1) and University of Zurich. We thank Dr. B. Spingler, Institute Inorganic Chemistry, Zurich, for helpful crystallographic discussions, S. Weyeneth, Physics Institute, assistance with magnetic measurements. are grateful to Prof. A. Stemmer R. Enning, Micro Nano Platform, ETH help AFM Wepf, Electron Microscopy EMEZ, Cryo-SEM investigations. The support Center Image Analysis, is gratefully acknowledged, we Y. Zhou, UZH, SEM

参考文章(46)
J. F. KEGGIN, Structure of the Molecule of 12-Phosphotungstic Acid Nature. ,vol. 131, pp. 908- 909 ,(1933) , 10.1038/131908B0
Michael Thor Pope, Heteropoly and isopoly oxometalates Inorganic chemistry concepts. ,vol. 8, ,(1983) , 10.1007/978-3-662-12004-0
Michael Thor Pope, Tshihiro Yamase, Polyoxometalate Chemistry For Nano- Composite Design ,(2009)
Bernold, Hasenknopf, Polyoxometalates: introduction to a class of inorganic compounds and their biomedical applications. Frontiers in Bioscience. ,vol. 10, pp. 275- 287 ,(2005) , 10.2741/1527
Ulrich Kortz, Masha G. Savelieff, Bassem S. Bassil, Michael H. Dickman, Ein großes, neuartiges Polyoxowolframat: [AsW65O217(H2O)7]26− Angewandte Chemie. ,vol. 113, pp. 3488- 3491 ,(2001) , 10.1002/1521-3757(20010917)113:18<3488::AID-ANGE3488>3.0.CO;2-R
Paul Kögerler, Manfred Speldrich, Colette Boskovic, Robert W. Gable, Firasat Hussain, Polyoxotungstate-encapsulated Gd6 and Yb10 complexes Chemical Communications. pp. 328- 330 ,(2009) , 10.1039/B813173B
R. D. Peacock, T. J. R. Weakley, Heteropolytungstate complexes of the lanthanide elements. Part I. Preparation and reactions Journal of the Chemical Society A: Inorganic, Physical, Theoretical. pp. 1836- 1839 ,(1971) , 10.1039/J19710001836
Anne Dolbecq, Jean‐Daniel Compain, Pierre Mialane, Jérôme Marrot, Francis Sécheresse, Bineta Keita, Luis Roberto Brudna Holzle, Frédéric Miserque, Louis Nadjo, None, Hexa‐ and Dodecanuclear Polyoxomolybdate Cyclic Compounds: Application toward the Facile Synthesis of Nanoparticles and Film Electrodeposition Chemistry: A European Journal. ,vol. 15, pp. 733- 741 ,(2009) , 10.1002/CHEM.200800719
Agata Trzesowska, Rafal Kruszynski, Tadeusz J. Bartczak, New bond-valence parameters for lanthanides Acta Crystallographica Section B-structural Science. ,vol. 60, pp. 174- 178 ,(2004) , 10.1107/S0108768104002678