ELECTROCHEMICAL REDUCTION OF CARBON DIOXIDE TO HYDROCARBONS WITH HIGH FARADAIC EFFICIENCY IN LIOH/METHANOL
作者： Satoshi Kaneco , Kenji Iiba , Syo-ko Suzuki , Kiyohisa Ohta , Takayuki Mizuno
DOI: 10.1021/JP990021J
关键词: Hydrocarbon 、 Methanol 、 Formic acid 、 Carbon monoxide 、 Inorganic chemistry 、 Methane 、 Chemistry 、 Electrochemical reduction of carbon dioxide 、 Potassium hydroxide 、 Lithium hydroxide
摘要: The electrochemical reduction of CO2 with a Cu electrode in LiOH/methanol-based electrolyte was investigated. A divided H-type cell employed, the supporting electrolytes were 80 mmol dm-3 lithium hydroxide methanol (catholyte) and 300 potassium (anolyte). main products from methane, ethylene, carbon monoxide, formic acid. maximum current efficiency for hydrocarbons (methane ethylene) 78%, at −4.0 V vs Ag/AgCl, saturated KCl. ratio methane/ethylene, rf(CH4)/rf(C2H4), range 2.2 to 4.3. In LiOH/methanol, hydrogen formation, competing reaction reduction, depressed below 2% relatively negative potentials. On basis this work, high hydrocarbon conversion method appears be achieved. Future work advance technology may include use solar energy as electric source. This research can contribute...
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Afgoustinos Anagnostopoulos, Georgios Kyriacou, Influence CO 2 partial pressure and the supporting electrolyte cation on the product distribution in CO 2 electroreduction Journal of Applied Electrochemistry. ,vol. 23, pp. 483- 486 ,(1993) , 10.1007/BF00707626
Masashi Azuma, Kazuhito Hashimoto, Masahiro Hiramoto, Masahiro Watanabe, Tadayoshi Sakata, Electrochemical Reduction of Carbon Dioxide on Various Metal Electrodes in Low‐Temperature Aqueous KHCO 3 Media Journal of The Electrochemical Society. ,vol. 137, pp. 1772- 1778 ,(1990) , 10.1149/1.2086796
David W. DeWulf, Tuo Jin, Allen J. Bard, Electrochemical and Surface Studies of Carbon Dioxide Reduction to Methane and Ethylene at Copper Electrodes in Aqueous Solutions Journal of The Electrochemical Society. ,vol. 136, pp. 1686- 1691 ,(1989) , 10.1149/1.2096993
Takayuki Mizuno, Akira Naitoh, Kiyohisa Ohta, Electrochemical reduction of CO2 in methanol at −30°C Journal of Electroanalytical Chemistry. ,vol. 391, pp. 199- 201 ,(1995) , 10.1016/0022-0728(95)03936-B
Ronald L. Cook, Robert C. MacDuff, Anthony F. Sammells, On the Electrochemical Reduction of Carbon Dioxide at In Situ Electrodeposited Copper Journal of The Electrochemical Society. ,vol. 135, pp. 1320- 1326 ,(1988) , 10.1149/1.2095972
Tomonori Saeki, Kazuhito Hashimoto, Naokazu Kimura, Koji Omata, Akira Fujishima, Electrochemical reduction of CO2 with high current density in a CO2 + methanol medium II. CO formation promoted by tetrabutylammonium cation Journal of Electroanalytical Chemistry. ,vol. 390, pp. 77- 82 ,(1995) , 10.1016/0022-0728(95)03897-P
Kaname Ito, Shoichiro Ikeda, Nobuhiro Yamauchi, Takaya Iida, Takehiko Takagi, Electrochemical Reduction Products of Carbon Dioxide at Some Metallic Electrodes in Nonaqueous Electrolytes Bulletin of the Chemical Society of Japan. ,vol. 58, pp. 3027- 3028 ,(1985) , 10.1246/BCSJ.58.3027
R. Ortiz, O.P. Márquez, J. Márquez, C. Gutiérrez, FTIR spectroscopy study of the electrochemical reduction of CO2 on various metal electrodes in methanol Journal of Electroanalytical Chemistry. ,vol. 390, pp. 99- 107 ,(1995) , 10.1016/0022-0728(95)03960-O
P. Friebe, P. Bogdanoff, N. Alonso-Vante, H. Tributsch, A Real-Time Mass Spectroscopy Study of the (Electro)chemical Factors Affecting CO2Reduction at Copper Journal of Catalysis. ,vol. 168, pp. 374- 385 ,(1997) , 10.1006/JCAT.1997.1606
Shoichiro Ikeda, Takehiko Takagi, Kaname Ito, Selective Formation of Formic Acid, Oxalic Acid, and Carbon Monoxide by Electrochemical Reduction of Carbon Dioxide Bulletin of the Chemical Society of Japan. ,vol. 60, pp. 2517- 2522 ,(1987) , 10.1246/BCSJ.60.2517