New preparation method of Lan+1NinO3n+1–δ (n=2, 3)

作者: Maria Deus Carvalho , Fernanda Madalena A. Costa , Isabel da Silva Pereira , Alain Wattiaux , Jean Marc Bassat

DOI: 10.1039/A702424J

关键词: Reactivity (chemistry)Inorganic chemistryTernary compoundOxygen stoichiometryNickel oxidesMorphology (linguistics)Preparation methodChemical preparationChemistryAnalytical chemistry

摘要: Samples Lan+1NinO3n+1–δ(n=2,3) have been prepared by two different methods, which lead to oxygen stoichiometry values. Materials obtained the citrate route always show higher content of Ni3+ , can be rationalized high reactivity and original morphology precursors this method.

参考文章(10)
A. Demourgues, F. Weill, B. Darriet, A. Wattiaux, J.C. Grenier, P. Gravereau, M. Pouchard, Additional Oxygen Ordering in "La2NiO4.25" (La8Ni4O17): I. Electron and Neutron Diffraction Study Journal of Solid State Chemistry. ,vol. 106, pp. 317- 329 ,(1993) , 10.1006/JSSC.1993.1292
A. Demourgues, F. Weill, J.C. Grenier, A. Wattiaux, M. Pouchard, Electron microscopy study of electrochemically prepared La2NiO4+δ (0.17≤δ≤0.26) Physica C-superconductivity and Its Applications. ,vol. 192, pp. 425- 434 ,(1992) , 10.1016/0921-4534(92)90849-8
Cesare Brisi, Mario Vallino, Fedele Abbattista, Composition and structure of two hitherto unidentified phases in the system La2O3-NiO-O Journal of The Less Common Metals. ,vol. 79, pp. 215- 219 ,(1981) , 10.1016/0022-5088(81)90070-9
K. Sreedhar, M. McElfresh, D. Perry, D. Kim, P. Metcalf, J.M. Honig, Low-Temperature Electronic Properties of the Lan+1NinO3n+1 (n = 2, 3, and ∞) System: Evidence for a Crossover from Fluctuating-Valence to Fermi-Liquid-like Behavior Journal of Solid State Chemistry. ,vol. 110, pp. 208- 215 ,(1994) , 10.1006/JSSC.1994.1161
P. Barboux, P. Griesmar, F. Ribot, L. Mazerolles, Homogeneity-Related Problems in Solution Derived Powders Journal of Solid State Chemistry. ,vol. 117, pp. 343- 350 ,(1995) , 10.1006/JSSC.1995.1283
Z. Zhang, M. Greenblatt, J.B. Goodenough, Synthesis, Structure, and Properties of the Layered Perovskite La3Ni2O7-δ Journal of Solid State Chemistry. ,vol. 108, pp. 402- 409 ,(1994) , 10.1006/JSSC.1994.1059
J. Drennan, C.P. Tavares, B.C.H. Steele, An electron microscope investigation of phases in the system LaNiO Materials Research Bulletin. ,vol. 17, pp. 621- 626 ,(1982) , 10.1016/0025-5408(82)90044-7
Z. Zhang, M. Greenblatt, Synthesis, Structure, and Physical Properties of La3-xMxNi2O7-δ (M = Ca2+, Sr2+, Ba2+; 0 < x ≤ 0.075) Journal of Solid State Chemistry. ,vol. 111, pp. 141- 146 ,(1994) , 10.1006/JSSC.1994.1209
Z. Zhang, M. Greenblatt, Synthesis, Structure, and Properties of Ln4Ni3O10-δ (Ln = La, Pr, and Nd) Journal of Solid State Chemistry. ,vol. 117, pp. 236- 246 ,(1995) , 10.1006/JSSC.1995.1269