Microwave spectra of methyl bromide and methyl bromide-d3. Coriolis resonance between the ν2 and ν5 states

作者: Yonezo Morino , Chiaki Hirose

DOI: 10.1016/0022-2852(67)90083-5

关键词: Atomic physicsBromideResonanceDegenerate energy levelsMicrowave spectraPhysicsExcited stateCoupling constantPhysical and Theoretical ChemistrySpectroscopyAtomic and Molecular Physics, and Optics

摘要: Abstract Microwave spectra of CH 3 79 Br, 81 CD and Br in various excited vibrational states have been measured. The vibration-rotation interaction constant α v B the change eQq coupling obtained for ν 2 , 5 6 + Br. It was found that l -type doublet first state degenerate vibration had unequal separations from central line. results are discussed terms Coriolis resonance between states.

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