作者: V.K. Tikhomirov , J. Méndez-Ramos , V.D. Rodríguez , D. Furniss , A.B. Seddon
DOI: 10.1016/J.OPTMAT.2005.06.017
关键词: Photon upconversion 、 Laser 、 Atomic physics 、 Spectroscopy 、 Emission spectrum 、 Absorption (electromagnetic radiation) 、 Stimulated emission 、 Analytical chemistry 、 Lasing threshold 、 Chemistry 、 Population inversion
摘要: Abstract The room temperature emission spectrum at about 2.7 μm corresponding to the laser transition 4I11/2 → 4I13/2 in Er3+-doped nano-scaled transparent oxyfluoride glass–ceramic has been measured and stimulated cross-section for calculated. intensity of found be 40 times stronger lifetime 50 longer glass–ceramics compared precursor glass, which we show due a change frequency phonon involved non-radiative de-excitation 4I11/2 level from 900 cm−1 glass 240 cm−1 ensuing glass–ceramics. absorption excited state 4I13/2 → 4I11/2 calculated based on experimental reciprocal wavelength dependence gain lasing vs population inversion derived. lasing/optical amplification parameters, such as inversion, pump saturation product fluorescence have obtained wavelength. A noteworthy result is that action possible these glass–ceramics, already not taking into account energy transfer or up-conversion processes, related 4I13/2 level, favour inversion.