Copolymers of (2‐cyclohexylidene‐1,3‐dioxolane‐4‐yl) methyl methacrylate with acrylonitrile and styrene: Synthesis, characterization, and monomer reactivity ratios
作者： Z�lf??ye ?lter , Mehmet Co?kun , ?brah??m Erol
DOI: 10.1002/POLA.1209
关键词: Styrene 、 Dioxolane 、 Differential scanning calorimetry 、 Thermogravimetric analysis 、 Copolymer 、 Polymer chemistry 、 Methyl methacrylate 、 Monomer 、 Chemistry 、 Acrylonitrile
摘要: The copolymerization of (2-cyclohexylidene-1,3-dioxolane-4-yl) methyl methacrylate monomer with styrene and acrylonitrile were carried out in 1,4-dioxane solution at 60 °C using BPO as an initiator. copolymers characterized by Fourier transform infrared, 1H NMR, 13C NMR spectroscopic techniques. Thermal properties the polymers also studied thermogravimetric analysis differential scanning calorimetry. copolymer compositions determined elemental analysis. monomer-reactivity ratios calculated application conventional linearization methods a result Fineman–Ross Kelen–Tudős to less than 1 for both monomers. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Chem 39: 2326–2331,
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sci-hub.se 参考文章(17)
Etienne Schacht, Guido Desmarets, Yvan Bogaert, Polymeric pesticides, 4. Synthesis of polyamides and a polyester containing 2,6‐dichlorobenzaldehyde Macromolecular Chemistry and Physics. ,vol. 179, pp. 837- 840 ,(1978) , 10.1002/MACP.1978.021790328
Etienne H. Schacht, Guido Desmarets, Thomas St. Pierre, Polymeric pesticides, 3. Synthesis and characterization of polyacetals prepared from α,ω‐diols and 2,6‐dichlorobenzaldehyde Macromolecular Chemistry and Physics. ,vol. 179, pp. 543- 548 ,(1978) , 10.1002/MACP.1978.021790231
Hiroyoshi Kamogawa, Yuichiro Haramoto, Masato Nanasawa, Syntheses of Polymerizable Acetals. II. Readily Hydrolyzable Acetals from Citronellol and Vitamins Bulletin of the Chemical Society of Japan. ,vol. 52, pp. 846- 848 ,(1979) , 10.1246/BCSJ.52.846
M Fernández-García, E.L Madruga, R Cuervo-Rodríguez, M.C Fernández-Monreal, Thermal properties of ethyl α-hydroxymethylacrylate-methyl methacrylate copolymers Polymer. ,vol. 35, pp. 4474- 4478 ,(1994) , 10.1016/0032-3861(94)90112-0
T. Usami, T. Itoh, H. Ohtani, Shin Tsuge, Structural study of polyacrylonitrile fibers during oxidative thermal degradation by pyrolysis-gas chromatography, solid-state carbon-13 NMR, and Fourier-transform infrared spectroscopy Macromolecules. ,vol. 23, pp. 2460- 2465 ,(1990) , 10.1021/MA00211A009
H.S. Fochler, J.R. Mooney, L.E. Ball, R.D. Boyer, J.G. Grasselli, Infrared and NMR spectroscopic studies of the thermal degradation of polyacrylonitrile Spectrochimica Acta Part A: Molecular Spectroscopy. ,vol. 41, pp. 271- 278 ,(1985) , 10.1016/0584-8539(85)80105-7
Mehmet Coşkun, Zülfiye Ilter, Eyüp Özdemir, Kadir Demirelli, Misir Ahmedzade, Synthesis, characterization and thermal degradation of poly[(2-phenyl-1,3-dioxolane-4-yl)methyl methacrylate] Polymer Degradation and Stability. ,vol. 60, pp. 185- 193 ,(1998) , 10.1016/S0141-3910(97)00065-7
Simona Morariu, Bogdan C. Simionescu, On the polymerization of 2-(2′,4′-dichlorophenyl)-4-methylene-1,3-dioxolane European Polymer Journal. ,vol. 30, pp. 1339- 1343 ,(1994) , 10.1016/0014-3057(94)90148-1
Simona Morariu, Emil C. Buruiana, Bogdan C. Simionescu, Free-radical ring-opening polymerization of 2-(o-chlorophenyl)-4-methylene-1,3-dioxolane Polymer Bulletin. ,vol. 30, pp. 7- 12 ,(1993) , 10.1007/BF00296227
Morton Fineman, Sidney D. Ross, Linear method for determining monomer reactivity ratios in copolymerization Journal of Polymer Science. ,vol. 5, pp. 259- 262 ,(1950) , 10.1002/POL.1950.120050210