Thermal properties of ethyl α-hydroxymethylacrylate-methyl methacrylate copolymers
作者： M Fernández-García , E.L Madruga , R Cuervo-Rodríguez , M.C Fernández-Monreal
DOI: 10.1016/0032-3861(94)90112-0
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摘要: Abstract The degradation and glass transition temperatures of a series methyl methacrylate (MMA)-ethyl α-hydroxymethylacrylate (EHMA) copolymers have been studied by t.g.a./i.r. d.s.c. Thermal yielded intramolecular lactone intermolecular crosslinking formation, with concurrent loss ethanol and/or methanol involving adjacent or near-neighbour EHMA MMA units. Glass transitions analysed as function sequence distribution their values compared to the theoretical ones derived using Johnston's equation. partially degraded increased consequence above mentioned formation.
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sci-hub.se 参考文章(25)
Jean Guillot, Brigitte Emelie, Modelling of the glass transition of random copolymers Die Makromolekulare Chemie, Rapid Communications. ,vol. 12, pp. 117- 126 ,(1991) , 10.1002/MARC.1991.030120209
H. James Harwood, W. M. Ritchey, The characterization of sequence distribution in copolymers Journal of Polymer Science Part B: Polymer Letters. ,vol. 2, pp. 601- 607 ,(1964) , 10.1002/POL.1964.110020607
N. W. Johnston, Sequence Distribution-Glass Transition Effects Journal of Macromolecular Science—Reviews in Macromolecular Chemistry. ,vol. 14, pp. 215- 250 ,(1976) , 10.1080/15321797608065770
Takashi Kashiwagi, Atsushi Inaba, James E. Brown, Koichi Hatada, Tatsuki Kitayama, Eiji Masuda, Effects of weak linkages on the thermal and oxidative degradation of poly(methyl methacrylates) Macromolecules. ,vol. 19, pp. 2160- 2168 ,(1986) , 10.1021/MA00162A010
A. Barlow, R.S. Lehrle, J.C. Robb, D. Sunderland, Polymethylmethacrylate degradation—Kinetics and mechanisms in the temperature range 340° to 460°C☆ Polymer. ,vol. 8, pp. 537- 545 ,(1967) , 10.1016/0032-3861(67)90065-1
M. Fernandez-Garcia, M. M. C. Lopez-Gonzalez, J. M. Barrales-Rienda, E. L. Madruga, C. Arias, Effect of copolymer composition and conversion on the glass transition of methyl acrylate–methyl methacrylate copolymers Journal of Polymer Science Part B: Polymer Physics. ,vol. 32, pp. 1191- 1203 ,(1994) , 10.1002/POLB.1994.090320707
Steven L. Hurley, Martin L. Mittleman, Charles A. Wilkie, Preparation and thermal degradation of copolymers of 2-sulfoethyl methacrylate and methyl methacrylate Polymer Degradation and Stability. ,vol. 39, pp. 345- 354 ,(1993) , 10.1016/0141-3910(93)90010-G
I. C. McNeill, T. Straiton, P. Anderson, Thermal degradation of poly(vinyl bromide), vinyl bromide‐methyl methacrylate copolymers, and poly(vinyl bromide)‐poly(methyl methacrylate) blends Journal of Polymer Science Part A. ,vol. 18, pp. 2085- 2101 ,(1980) , 10.1002/POL.1980.170180706
Masaaki Hirooka, Takashi Kato, Glass transition temperature and sequential structure of equimolar copolymers Journal of Polymer Science: Polymer Letters Edition. ,vol. 12, pp. 31- 37 ,(1974) , 10.1002/POL.1974.130120106
E. A. Dimarzio, J. H. Gibbs, Glass temperature of copolymers Journal of Polymer Science. ,vol. 40, pp. 121- 131 ,(1959) , 10.1002/POL.1959.1204013609