Experimental studies on hydrogenation of anthraquinone derivative in a microreactor

作者: Raghunath Halder , Adeniyi Lawal

DOI: 10.1016/J.CATTOD.2007.03.055

关键词: PalladiumYield (chemistry)CatalysisChemistryAnthraquinoneHeterogeneous catalysisChemical engineeringMicroreactorHydrogenPhotochemistryHydrogen peroxideGeneral chemistry

摘要: … The non-polar solvent is 1,3,5 trimethylbenzene, and the polar solvent is trioctyl phosphate. The EAQ, 1,3,5 trimethylbenzene and trioctyl phosphate (all reagent grade), were purchased …

参考文章(14)
A. Drelinkiewicz, R. Laitinen, R. Kangas, J. Pursiainen, 2-Ethylanthraquinone hydrogenation on Pd/Al2O3 The effect of water and NaOH on the degradation process Applied Catalysis A-general. ,vol. 284, pp. 59- 67 ,(2005) , 10.1016/J.APCATA.2005.01.018
Raymond Eller Kirk, Donald Frederick Othmer, Encyclopedia of Chemical Technology ,(1998)
E. Santacesaria, M. Di Serio, A. Russo, U. Leone, R. Velotti, Kinetic and catalytic aspects in the hydrogen peroxide production via anthraquinone Chemical Engineering Science. ,vol. 54, pp. 2799- 2806 ,(1999) , 10.1016/S0009-2509(98)00377-7
R. Edvinsson Albers, M. Nyström, M. Siverström, A. Sellin, A.-C. Dellve, U. Andersson, W. Herrmann, Th. Berglin, Development of a monolith-based process for H2O2 production: from idea to large-scale implementation Catalysis Today. ,vol. 69, pp. 247- 252 ,(2001) , 10.1016/S0920-5861(01)00376-5
E. Santacesaria, P. Wilkinson, P. Babini, S. Carra, Hydrogenation of 2-ethyltetrahydroanthraquinone in the presence of palladium catalyst Industrial & Engineering Chemistry Research. ,vol. 27, pp. 780- 784 ,(1988) , 10.1021/IE00077A011
Sunitha Tadepalli, Dongying Qian, Adeniyi Lawal, Comparison of performance of microreactor and semi-batch reactor for catalytic hydrogenation of o-nitroanisole Catalysis Today. ,vol. 125, pp. 64- 73 ,(2007) , 10.1016/J.CATTOD.2007.01.076
E. Santacesaria, M. Di Serio, R. Velotti, U. Leone, Kinetics, Mass Transfer, and Palladium Catalyst Deactivation in the Hydrogenation Step of the Hydrogen Peroxide Synthesis via Anthraquinone Industrial & Engineering Chemistry Research. ,vol. 33, pp. 277- 284 ,(1994) , 10.1021/IE00026A016
C. J. King, Limin Hsueh, Kao-Wen Mao, Liquid Phase Diffusion of Non-electrolytes at High Dilution. Journal of Chemical & Engineering Data. ,vol. 10, pp. 348- 350 ,(1965) , 10.1021/JE60027A014