Ozone production efficiency of a ship-plume: ITCT 2K2 case study.
作者： Hyun S. Kim , Yong H. Kim , Kyung M. Han , Jhoon Kim , Chul H. Song
DOI: 10.1016/J.CHEMOSPHERE.2015.05.022
关键词: Atmospheric sciences 、 Plume 、 Chemistry 、 Marine boundary layer 、 Chemical evolution 、 Ozone 、 Production efficiency 、 Air pollutants
摘要: Ozone production efficiency (OPE) of ship plume was first evaluated in this study, based on ship-plume photochemical/dynamic model simulations and the composition data measured during ITCT 2K2 (Intercontinental Transport Chemical Transformation 2002) aircraft campaign. The averaged instantaneous OPEs (OPE(i)‾) estimated via modeling for ranged between 4.61 18.92, showing that values vary with extent chemical evolution (or stage) stability classes marine boundary layer (MBL). Together OPE(i)‾, equivalent (OPE(e)‾) entire were also estimated. OPE(e)‾ varied 9.73 (for stable MBL) 12.73 moderately MBL), which agreed well 12.85 observations. It found both model-simulated observation-based inside 0.29-0.38 times smaller than calculated/measured outside ship-plume. Such low insides due to high levels NO non-liner photochemistry. Possible implications OPE study global chemistry-transport are discussed.
elsevier.com
harvard.edu
core.ac.uk 
sci-hub.se 参考文章(24)
Mark G Lawrence, Paul J Crutzen, None, Influence of NOx emissions from ships on tropospheric photochemistry and climate Nature. ,vol. 402, pp. 167- 170 ,(1999) , 10.1038/46013
A. R. Rickard, G. Salisbury, P. S. Monks, A. C. Lewis, S. Baugitte, B. J. Bandy, K. C. Clemitshaw, S. A. Penkett, Comparison of Measured Ozone Production Efficiencies in the Marine Boundary Layer at Two European Coastal Sites under Different Pollution Regimes Journal of Atmospheric Chemistry. ,vol. 43, pp. 107- 134 ,(2002) , 10.1023/A:1019970123228
Kevin Capaldo, James J Corbett, Prasad Kasibhatla, Paul Fischbeck, Spyros N Pandis, None, Effects of ship emissions on sulphur cycling and radiative climate forcing over the ocean Nature. ,vol. 400, pp. 743- 746 ,(1999) , 10.1038/23438
R.G. Derwent, T.J. Davies, Modelling the impact of NOx or hydrocarbon control on photochemical ozone in Europe Atmospheric Environment. ,vol. 28, pp. 2039- 2052 ,(1994) , 10.1016/1352-2310(94)90472-3
Chul H Song, Gao Chen, Douglas D Davis, Chemical evolution and dispersion of ship plumes in the remote marine boundary layer: investigation of sulfur chemistry Atmospheric Environment. ,vol. 37, pp. 2663- 2679 ,(2003) , 10.1016/S1352-2310(03)00198-5
Lawrence I Kleinman, Peter H Daum, Jai H Lee, Yin‐Nan Lee, Linda J Nunnermacker, Stephen R Springston, Leonard Newman, Judith Weinstein‐Lloyd, Sanford Sillman, None, Dependence of ozone production on NO and hydrocarbons in the troposphere Geophysical Research Letters. ,vol. 24, pp. 2299- 2302 ,(1997) , 10.1029/97GL02279
Sanford Sillman, Jennifer A. Logan, Steven C. Wofsy, The sensitivity of ozone to nitrogen oxides and hydrocarbons in regional ozone episodes Journal of Geophysical Research. ,vol. 95, pp. 1837- 1851 ,(1990) , 10.1029/JD095ID02P01837
CH Song, G Chen, SR Hanna, J Crawford, DD Davis, Dispersion and chemical evolution of ship plumes in the marine boundary layer: Investigation of O3/NOy/HOxchemistry Journal of Geophysical Research. ,vol. 108, pp. 4143- ,(2003) , 10.1029/2002JD002216
S. C. Liu, M. Trainer, F. C. Fehsenfeld, D. D. Parrish, E. J. Williams, D. W. Fahey, G. Hübler, P. C. Murphy, Ozone production in the rural troposphere and the implications for regional and global ozone distributions Journal of Geophysical Research. ,vol. 92, pp. 4191- 4207 ,(1987) , 10.1029/JD092ID04P04191
L. J. Carpenter, T. J. Green, G. P. Mills, S. Bauguitte, S. A. Penkett, P. Zanis, E. Schuepbach, N. Schmidbauer, P. S. Monks, C. Zellweger, Oxidized nitrogen and ozone production efficiencies in the springtime free troposphere over the Alps web science. ,vol. 105, pp. 14547- 14559 ,(2000) , 10.1029/2000JD900002