Study on the Electrolyte Added Chlorosulfuric Acid for All-vanadium Redox Flow Battery

作者: YONG-HWAN OH , GEON-WOO LEE , CHEOL-HWI RYU , GAB-JIN HWANG

DOI: 10.7316/KHNES.2016.27.2.169

关键词: VanadiumChlorosulfuric acidThermal stabilityInorganic chemistryFlow batteryCyclic voltammetryBattery (electricity)ElectrolyteMaterials scienceLithium vanadium phosphate battery

摘要: >> The electrolyte added the chlorosulfuric acid (HSO3Cl) as an additive was tested for in all-vanadium redox flow battery (VRFB) to increase thermal stability of electrolyte. property measured by CV (cyclic voltammetry) method. maximum value a voltage and current density HSO3Cl higher than that non-added HSO3Cl. pentavalent vanadium ion solution, which at 40°C, increased adding performances VRFB using were during 30 cycles charge-discharge 60 mA/cm 2 . An average energy efficiency 72.5%, 82.4%, 81.6% HSO3Cl, 0.5 mol 1.0 respectively. showed performance

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