Synthesis, crystal structure and magnetic properties of [Cu(bipy)2(CH3COO)][Cu(bipy)2(Cr(C2O4)3)]·∼10.5H2O, the first compound containing the [Cr(C2O4)3]3− building block acting as a monodentate ligand

作者: Otilia Costisor , Kurt Mereiter , Miguel Julve , Francesc Lloret , Yves Journaux

DOI: 10.1016/S0020-1693(01)00569-2

关键词: 2,2'-BipyridineCrystallographyInorganic chemistryDenticityTrigonal bipyramidal molecular geometryCopperMagnetic susceptibilityCrystal structureStackingCationic polymerizationChemistry

摘要: The reaction between copper(II) acetate with 2,2′-bipyridine and K 3 [Cr(C 2 O 4 ) 3 ] leads to the novel salt [Cu(bipy) 2 (CH 3 COO)][Cu(bipy) 2 (Cr(C 2 O 4 ) 3 )]·∼10.5H 2 O, 1 (bipy=2…

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