Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate
作者： Hai-Xing Liu , Fang-Fang Jian , Jing Wang
DOI: 10.1107/S160053680900823X
关键词:
摘要: In the title compound, [Cd2Cr2O8(C12H8N2)4]·2H2O, which was obtained by hydrothermal reaction of CdCO3 and phenanthroline with K2CrO4 at 393 K, two distorted Cd(N4O2) octahedra are linked through μ2-bridging chromate anions, forming a centrosymmetric tetranuclear eight-membered ring complex. The water molecules link O atoms via intermolecular O—H⋯O hydrogen bonds. These aggregates pack to three-dimensional network weak C—H⋯O C—H⋯π hydrogen-bonding contacts.
sci-hub.st 参考文章(7)
Grigore A. Timco, Andrei S. Batsanov, Finn K. Larsen, Christopher A. Muryn, Jacob Overgaard, Simon J. Teat, Richard E. P. Winpenny, Influencing the nuclearity and constitution of heterometallic rings via templates Chemical Communications. pp. 3649- 3651 ,(2005) , 10.1039/B504912A
Hirofumi Yoshikawa, Shin-ichi Nishikiori, Tokuko Watanabe, Toshimasa Ishida, Go Watanabe, Makoto Murakami, Kinga Suwinska, Roman Luboradzki, Janusz Lipkowski, Polycyano–polycadmate host clathrates including a methylviologen dication. Syntheses, crystal structures and photo-induced reduction of methylviologen dication Journal of The Chemical Society-dalton Transactions. pp. 1907- 1917 ,(2002) , 10.1039/B111059D
Otilia Costisor, Kurt Mereiter, Miguel Julve, Francesc Lloret, Yves Journaux, Wolfgang Linert, Marius Andruh, Synthesis, crystal structure and magnetic properties of [Cu(bipy)2(CH3COO)][Cu(bipy)2(Cr(C2O4)3)]·∼10.5H2O, the first compound containing the [Cr(C2O4)3]3− building block acting as a monodentate ligand Inorganica Chimica Acta. ,vol. 324, pp. 352- 358 ,(2001) , 10.1016/S0020-1693(01)00569-2
Phalguni Chaudhuri, Manuela Winter, Karl Wieghardt, Stefan Gehring, Wolfgang Haase, Bernhard Nuber, Johannes Weiss, Syntheses and magnetic properties of a heteropolyoxotungsten(VI)iron(III) cation and [LFeIII(.mu.-MO4)3FeIIIL] complexes (M = chromium(VI), molybdenum(VI)). Crystal structures of L2Fe2(CrO4)3.cntdot.H2O and [L3Fe3W4O14(OCH3)3](ClO4)2.cntdot.0.5H2O (L = 1,4,7-trimethyl-1,4,7-triazacyclononane) Inorganic Chemistry. ,vol. 27, pp. 1564- 1569 ,(1988) , 10.1021/IC00282A011
Jing-Cao Dai, Xin-Tao Wu, Zhi-Yong Fu, Chuan-Peng Cui, Sheng-Min Hu, Wen-Xin Du, Li-Ming Wu, Han-Hui Zhang, Rui-Qing Sun, Synthesis, structure, and fluorescence of the novel cadmium(II)-trimesate coordination polymers with different coordination architectures. Inorganic Chemistry. ,vol. 41, pp. 1391- 1396 ,(2002) , 10.1021/IC010794Y
George M. Sheldrick, A short history of SHELX Acta Crystallographica Section A. ,vol. 64, pp. 112- 122 ,(2008) , 10.1107/S0108767307043930
Finn K. Larsen, Eric J. L. McInnes, Hassane El Mkami, Jacob Overgaard, Stergios Piligkos, Gopalan Rajaraman, Eva Rentschler, Andrew A. Smith, Graham M. Smith, Val Boote, Martin Jennings, Grigore A. Timco, Richard E. P. Winpenny, Synthesis and Characterization of Heterometallic{Cr7M} Wheels Angewandte Chemie International Edition. ,vol. 42, pp. 101- 105 ,(2003) , 10.1002/ANIE.200390034