Potassium solubility in metal: the effects of composition at 15 kbar and 1900°C on partitioning between iron alloys and silicate melts

作者: Nancy L Chabot , Michael J Drake

DOI: 10.1016/S0012-821X(99)00208-3

关键词: Mineral redox bufferGeologyMineralogyElectron microprobeAnalytical chemistryMetalEnergy sourceHeat generationSilicateSolubilityPartition coefficient

摘要: Abstract To determine the role of radioactive heating as an energy source in planetary cores, solubility K metal has been examined experimentally. All experiments were conducted at 15 kbar and 1900°C involved partitioning between Fe alloys silicate melts. Experiments with different concentrations S metallic liquid indicate that increases metal. Unlike S, presence C does not increase to a level detectable electron microprobe. The composition significantly affects S-rich metal, metal/silicate partition coefficient for increasing by nearly two orders magnitude depolymerization melt. Using appropriate early, differentiating Earth assuming is significant light element core, 6×10−3 1900°C. Such value, if representative behavior core formation conditions, suggests less than 1 ppm Earth's present-day heat generation 1010 W, which 2–3 lower estimates power necessary drive geodynamo. Other thermodynamic variables, namely pressure, temperature, oxygen fugacity may also affect

参考文章(39)
Bjorn O. Mysen, Relations Between Structure, Redox Equilibria of Iron, and Properties of Magmatic Liquids Advances in Physical Geochemistry. ,vol. 9, pp. 41- 98 ,(1991) , 10.1007/978-1-4612-3128-8_2
Henry T. Hall, V. Rama Murthy, The early chemical history of the earth: Some critical elemental fractionations Earth and Planetary Science Letters. ,vol. 11, pp. 239- 244 ,(1971) , 10.1016/0012-821X(71)90170-1
Eiji Ohtani, Takumi Kato, Kosuke Onuma, Eiji Ito, Partitioning of Elements Between Mantle and Core Materials and Early Differentiation of the Earth Washington DC American Geophysical Union Geophysical Monograph Series. ,vol. 67, pp. 341- 349 ,(2013) , 10.1029/GM067P0341
Eiji Ohtani, Hisayoshi Yurimoto, Shuji Seto, Element partitioning between metallic liquid, silicate liquid, and lower-mantle minerals: implications for core formation of the Earth Physics of the Earth and Planetary Interiors. ,vol. 100, pp. 97- 114 ,(1997) , 10.1016/S0031-9201(96)03234-7
Jibamitra Ganguly, George C. Kennedy, Solubility of K in Fe-S liquid, silicate-K-(Fe-S) liq equilibria, and their planetary implications Earth and Planetary Science Letters. ,vol. 35, pp. 411- 420 ,(1977) , 10.1016/0012-821X(77)90074-7
M. S. T. Bukowinski, The effect of pressure on the physics and chemistry of potassium Geophysical Research Letters. ,vol. 3, pp. 491- 494 ,(1976) , 10.1029/GL003I008P00491
John S. Lewis, Consequences of the presence of sulfur in the core of the earth Earth and Planetary Science Letters. ,vol. 11, pp. 130- 134 ,(1971) , 10.1016/0012-821X(71)90154-3
Paul Wallace, Ian S.E. Carmichael, Sulfur in basaltic magmas Geochimica et Cosmochimica Acta. ,vol. 56, pp. 1863- 1874 ,(1992) , 10.1016/0016-7037(92)90316-B