Mössbauer study of Fe mineralogy with respect to rank, type and Colombian carboniferous zone

作者: F. Reyes Caballero , S. A. Martínez Ovalle , M. Díaz Lagos , O. P. Gómez , A. Blandón

DOI: 10.1007/S10751-017-1420-Z

关键词: CoalMaceralMineralogyPyriteAnkeriteCarboniferousIlliteSideriteGeologyMineral

摘要: The transmission mode of Fe-57 Mossbauer spectroscopy was used to identify iron bearing minerals and establish relationships between among these the ranks types various carboniferous zones in Colombia. Maceral mineral compositions vary significantly Colombian zones. These variations determine some final characteristics potential uses coal, therefore contribute defining coal quality. A comparison results shows that thermal maturity coals ranges from lignite semianthracite. Similarities differences exist with respect conventional parameters. Cordoba Cauca have higher sulfur contents > 2 % ash contents. Iron identified included pyrite, which was, found everywhere, illite, ankerite, siderite, sulfates were particular areas. Coals Valle del Cauca, Cordoba, Caldas Santander are characterized by oxidation pyrite its transformation into ferrous or ferric sulfate.

参考文章(14)
F. Reyes Caballero, S. A. Martínez Ovalle, M. Moreno Gutiérrez, Mössbauer characterization of feed coal, ash and fly ash from a thermal power plant Hyperfine Interactions. ,vol. 232, pp. 141- 148 ,(2015) , 10.1007/S10751-015-1140-1
Michael E. Brownfield, Ronald H. Affolter, James D. Cathcart, Samuel Y. Johnson, Isabelle K. Brownfield, Cynthia A. Rice, Geologic setting and characterization of coals and the modes of occurrence of selected elements from the Franklin coal zone, Puget Group, John Henry No. 1 mine, King County, Washington, USA International Journal of Coal Geology. ,vol. 63, pp. 247- 275 ,(2005) , 10.1016/J.COAL.2005.03.021
Clarence Karr, Analytical methods for coal and coal products Academic Press. ,(1978)
F. Reyes, G. A. Pérez Alcázar, J. M. Barraza, A. Bohórquez, J. A. Tabares, N. L. Speziali, Mössbauer and XRD Characterization of the Mineral Matter of Coal from the Guachinte Mine in Colombia Hyperfine Interactions. ,vol. 148/149, pp. 39- 46 ,(2003) , 10.1023/B:HYPE.0000003762.84005.29
Rajender Gupta, Advanced Coal Characterization: A Review† Energy & Fuels. ,vol. 21, pp. 451- 460 ,(2007) , 10.1021/EF060411M
Stanislav V. Vassilev, Juan M. D. Tascón, Methods for characterization of inorganic and mineral matter in coal: A critical overview Energy & Fuels. ,vol. 17, pp. 271- 281 ,(2003) , 10.1021/EF020113Z
John F Lefelhocz, Robert A Friedel, Truman P Kohman, Mössbauer spectroscopy of iron in coal Geochimica et Cosmochimica Acta. ,vol. 31, pp. 2261- 2273 ,(1967) , 10.1016/0016-7037(67)90001-4
Robert B Finkelman, Peggy M.K Gross, The types of data needed for assessing the environmental and human health impacts of coal International Journal of Coal Geology. ,vol. 40, pp. 91- 101 ,(1999) , 10.1016/S0166-5162(98)00061-5
F. Reyes Caballero, S. A. Martínez Ovalle, Mössbauer study of the inorganic sulfur removal from coals Hyperfine Interactions. ,vol. 224, pp. 263- 270 ,(2014) , 10.1007/S10751-013-0874-X