Mössbauer characterization of feed coal, ash and fly ash from a thermal power plant

作者: F. Reyes Caballero , S. A. Martínez Ovalle , M. Moreno Gutiérrez

DOI: 10.1007/S10751-015-1140-1

关键词: Fly ashCoal combustion productsHematiteMetallurgyPyriteMineralogyMagnetiteMaterials scienceJarositeThermal power stationCoal

摘要: The aim of this work was apply 57Fe Transmission Mossbauer Spectroscopy at room temperature in order to study the occurrence iron-containing mineral phases in: 1) feed coal; 2) coal ash, obtained different stages ASTM D3174 standard method; and 3) fly produced when is burned TERMOPAIPA IV thermal power plant localized Boyaca, Colombia. According results, we can conclude pyrite jarosite Fe2+ Fe3+ crystalline paramagnetic phases, superparamagnetic hematite ash; noncrystalline magnetite ash. Precisely, for a basic understanding, discusses some possible transformations that take place during combustion.

参考文章(18)
F.E. Huggins, G.P. Huffman, Mössbauer Analysis of Iron-Bearing Phases in Coal, Coke, and Ash Analytical Methods for Coal and Coal Products#R##N#Volume III. pp. 371- 423 ,(1979) , 10.1016/B978-0-12-399903-0.50019-2
Zhe Li, John Gehret Stevens, J. W. Miller, Herman Pollak, Airat M. Khasanov, Mössbauer mineral handbook Mössbauer Effect Data Center. ,(2005)
Yun Xia, Daniel I. Massé, Tim A. McAllister, Yunhong Kong, Robert Seviour, Carole Beaulieu, Identity and diversity of archaeal communities during anaerobic co-digestion of chicken feathers and other animal wastes Bioresource Technology. ,vol. 110, pp. 111- 119 ,(2012) , 10.1016/J.BIORTECH.2012.01.107
Stanislav V. Vassilev, Christina G. Vassileva, Methods for Characterization of Composition of Fly Ashes from Coal-Fired Power Stations: A Critical Overview Energy & Fuels. ,vol. 19, pp. 1084- 1098 ,(2005) , 10.1021/EF049694D
S. P. Taneja, Mössbauer Studies of Thermal Power Plant Coal and Fly Ash Hyperfine Interactions. ,vol. 153, pp. 83- 90 ,(2004) , 10.1023/B:HYPE.0000024715.55347.FE
Clarence Karr, Analytical methods for coal and coal products Academic Press. ,(1978)
D COLE, G SIMMONS, R HERMAN, K KLIER, I CZAKONAGY, Transformations of iron minerals during coal oxidation Fuel. ,vol. 66, pp. 1240- 1248 ,(1987) , 10.1016/0016-2361(87)90062-7
R.S. Blissett, N.A. Rowson, A review of the multi-component utilisation of coal fly ash Fuel. ,vol. 97, pp. 1- 23 ,(2012) , 10.1016/J.FUEL.2012.03.024
Omotola Babajide, Nicholas Musyoka, Leslie Petrik, Farouk Ameer, Novel zeolite Na-X synthesized from fly ash as a heterogeneous catalyst in biodiesel production Catalysis Today. ,vol. 190, pp. 54- 60 ,(2012) , 10.1016/J.CATTOD.2012.04.044