Magnetic properties of six-coordinated high-spin cobalt(II) complexes: Theoretical background and its application

作者: Francesc Lloret , Miguel Julve , Joan Cano , Rafael Ruiz-García , Emilio Pardo

DOI: 10.1016/J.ICA.2008.03.114

关键词: Physical chemistryMatrix (mathematics)Magnetic susceptibilityMagnetic anisotropySpin (physics)Spin–orbit interactionInductive couplingChemistryAtmospheric temperature rangeIonCondensed matter physics

摘要: … Firstly, we describe the magnetic properties of a cobalt(II) ion in an octahedral … the magnetic data of the high-spin cobalt(II) complexes, as well as to check their influence on the magnetic …

参考文章(68)
Lucia Banci, Alessandro Bencini, Cristiano Benelli, Dante Gatteschi, Claudia Zanchini, Spectral-structural correlations in high-spin cobalt(II) complexes Springer, Berlin, Heidelberg. pp. 37- 86 ,(1982) , 10.1007/BFB0111296
S. Sugano, R. G. Shulman, Covalency Effects in KNi F 3 . III. Theoretical Studies Physical Review. ,vol. 130, pp. 517- 530 ,(1963) , 10.1103/PHYSREV.130.517
Laura Cañadillas-Delgado, Oscar Fabelo, Jorge Pasán, Fernando S. Delgado, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez, Unusual (μ-aqua)bis(μ-carboxylate) Bridge in Homometallic M(II) (M = Mn, Co and Ni) Two-Dimensional Compounds Based on the 1,2,3,4-Butanetetracarboxylic Acid: Synthesis, Structure, and Magnetic Properties Inorganic Chemistry. ,vol. 46, pp. 7458- 7465 ,(2007) , 10.1021/IC7006765
Juan Manuel Herrera, Anne Bleuzen, Yves Dromzée, Miguel Julve, Francesc Lloret, Michel Verdaguer, Crystal structures and magnetic properties of two octacyanotungstate(IV) and (V)-cobalt(II) three-dimensional bimetallic frameworks. Inorganic Chemistry. ,vol. 42, pp. 7052- 7059 ,(2003) , 10.1021/IC034188+
E. Pardo, R. Ruiz-García, F. Lloret, J. Faus, M. Julve, Y. Journaux, F. Delgado, C. Ruiz-Pérez, Cobalt(II)-copper(II) bimetallic chains as a new class of single-chain magnets Advanced Materials. ,vol. 16, pp. 1597- 1600 ,(2004) , 10.1002/ADMA.200400253
Petra J. Van Koningsbruggen, Olivier Kahn, Keitaro Nakatani, Yu Pei, Jean Pierre Renard, Marc Drillon, Patrick Legoll, Magnetism of A-copper(II) bimetallic chain compounds (A = iron, cobalt, nickel): one- and three-dimensional behaviors. Inorganic Chemistry. ,vol. 29, pp. 3325- 3331 ,(1990) , 10.1021/IC00343A014
Juan J. Borras-Almenar, Eugenio Coronado, Dante Gatteschi, Claudia Zanchini, Anisotropic exchange and dimerization in the ordered bimetallic chains Co2(EDTA).6H2O and CoCu(EDTA).6H2O. Single-crystal EPR investigation Inorganic Chemistry. ,vol. 31, pp. 294- 298 ,(1992) , 10.1021/IC00028A031