Catalyst-free N-methylation of amines using CO2.

作者: Huiying Niu , Lijun Lu , Renyi Shi , Chien-Wei Chiang , Aiwen Lei

DOI: 10.1039/C6CC09072A

关键词: N methylationYield (chemistry)ReagentCatalysisChemistryMethylationOrganic chemistryMethylamines

摘要: … In this study, we have developed a catalyst-free N-methylation … under 1 atm of CO 2 in DMF at 90 C. Aliphatic and aromatic … of CO 2 could be promoted through solvation and polarization…

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