Reductive formylation of amines with CO2 using sodium borohydride: A catalyst-free route
作者： Leiduan Hao , Hongye Zhang , Xiaoying Luo , Cailing Wu , Yanfei Zhao
DOI: 10.1016/J.JCOU.2017.10.007
关键词:
摘要: Using sodium borohydride (NaBH 4 ) as the reducing reagent, the reductive fomylation of amines with CO 2 was realized at 100 C under catalyst-free conditions, and a series of …
sci-hub.se 参考文章(38)
Bo Yu, Hongye Zhang, Yanfei Zhao, Sha Chen, Jilei Xu, Changliang Huang, Zhimin Liu, Cyclization of o-phenylenediamines by CO2 in the presence of H2 for the synthesis of benzimidazoles Green Chemistry. ,vol. 15, pp. 95- 99 ,(2013) , 10.1039/C2GC36517K
Xinjiang Cui, Yan Zhang, Youquan Deng, Feng Shi, Amine formylation via carbon dioxide recycling catalyzed by a simple and efficient heterogeneous palladium catalyst Chemical Communications. ,vol. 50, pp. 189- 191 ,(2014) , 10.1039/C3CC46427J
Ciera Gerack, Lisa McElwee-White, Formylation of amines. Molecules. ,vol. 19, pp. 7689- 7713 ,(2014) , 10.3390/MOLECULES19067689
Mingyuan He, Yuhan Sun, Buxing Han, Green Carbon Science: Scientific Basis for Integrating Carbon Resource Processing, Utilization, and Recycling Angewandte Chemie International Edition. ,vol. 52, pp. 9620- 9633 ,(2013) , 10.1002/ANIE.201209384
Jinli Liu, Chengkun Guo, Zhaofu Zhang, Tao Jiang, Huizhen Liu, Jinliang Song, Honglei Fan, Buxing Han, Synthesis of dimethylformamide from CO2, H2 and dimethylamine over Cu/ZnO Chemical Communications. ,vol. 46, pp. 5770- 5772 ,(2010) , 10.1039/C0CC00751J
C. S. Lin, R. Q. Zhang, C. S. Lee, T. A. Niehaus, Th. Frauenheim, Geometric and excited-state properties of 1,4-bis(benzothiazolylvinyl)benzene interacting with 2,2',2' '-(1,3,5-phenylene)tris[1-phenyl-1H-benzimidazole] studied by a density-functional tight-binding method. Journal of Physical Chemistry B. ,vol. 110, pp. 20847- 20851 ,(2006) , 10.1021/JP061864V
Olivier Jacquet, Xavier Frogneux, Christophe Das Neves Gomes, Thibault Cantat, CO2 as a C1-building block for the catalytic methylation of amines Chemical Science. ,vol. 4, pp. 2127- 2131 ,(2013) , 10.1039/C3SC22240C
Ken Motokura, Naoki Takahashi, Daiki Kashiwame, Sho Yamaguchi, Akimitsu Miyaji, Toshihide Baba, None, Copper-diphosphine complex catalysts for N-formylation of amines under 1 atm of carbon dioxide with polymethylhydrosiloxane Catalysis Science & Technology. ,vol. 3, pp. 2392- 2396 ,(2013) , 10.1039/C3CY00375B
Catriona G. Mortimer, Geoffrey Wells, Jean-Philippe Crochard, Erica L. Stone, Tracey D. Bradshaw, Malcolm F. G. Stevens, Andrew D. Westwell, Antitumor benzothiazoles. 26.(1) 2-(3,4-dimethoxyphenyl)-5-fluorobenzothiazole (GW 610, NSC 721648), a simple fluorinated 2-arylbenzothiazole, shows potent and selective inhibitory activity against lung, colon, and breast cancer cell lines. Journal of Medicinal Chemistry. ,vol. 49, pp. 179- 185 ,(2006) , 10.1021/JM050942K
Xinjiang Cui, Xingchao Dai, Yan Zhang, Youquan Deng, Feng Shi, Methylation of amines, nitrobenzenes and aromatic nitriles with carbon dioxide and molecular hydrogen Chemical Science. ,vol. 5, pp. 649- 655 ,(2014) , 10.1039/C3SC52676C