The renovated silver ring electrode
作者： Bogusław Baś
DOI: 10.1016/J.ELECOM.2007.10.024
关键词: Stripping (chemistry) 、 Analytical chemistry 、 Underpotential deposition 、 Chemistry 、 Working electrode 、 Electrochemistry 、 Voltammetry 、 Electrode 、 Point of zero charge 、 Electrolyte
摘要: Abstract In this preliminary note, a new type of working electrode – the renovated silver ring (RSRE) is presented. The main constituents RSRE: specially constructed electrode, sheet used as counter/quasi-reference and silicon O-ring are fastened together in polypropylene body. renovation carried out through mechanical removal solid contaminants electrochemical activation electrolyte which fills RSRE effectiveness procedure was tested by designating RF E pzc recording C d t curves. As shown on selected examples, exhibits good performance underpotential deposition stripping voltammetry (UPD-SV) applied for determination Pb(II) traces certified reference materials.
elsevier.com
sci-hub.se 参考文章(15)
Petr Zuman, I. M. Kolthoff, Louis Meites, Progress in polarography ,(1962)
Jerzy Sobkowski, Andrzej Więckowski, A new approach to the radiometric study of methanol adsorption on platinum Journal of Electroanalytical Chemistry. ,vol. 34, pp. 185- 189 ,(1972) , 10.1016/S0022-0728(72)80513-8
Joseph T. Hupp, D. Larkin, Michael J. Weaver, Specific adsorption of halide and pseudohalide ions at electrochemically roughened versus smooth silver-aqueous interfaces Surface Science. ,vol. 125, pp. 429- 451 ,(1983) , 10.1016/0039-6028(83)90576-9
Sławomir Smoliński, Piotr Zelenay, Jerzy Sobkowski, Effect of surface order on adsorption of sulfate ions on silver electrodes Journal of Electroanalytical Chemistry. ,vol. 442, pp. 41- 47 ,(1998) , 10.1016/S0022-0728(97)00469-5
Roger Parsons, F.G.R. Zobel, The interphase between mercury and aqueous sodium dihydrogen phosphate Journal of Electroanalytical Chemistry. ,vol. 9, pp. 333- 348 ,(1965) , 10.1016/0022-0728(65)85029-X
R.M. Cerviño, W.E. Triaca, A.J. Arvia, Electrochemical preparation and characteristics of platinum electrode surfaces with preferred orientations Journal of Electroanalytical Chemistry. ,vol. 182, pp. 51- 60 ,(1985) , 10.1016/0368-1874(85)85439-3
Mordechai Brand, Inna Eshkenazi, Emilia Kirowa-Eisner, The Silver Electrode in Square-Wave Anodic Stripping Voltammetry. Determination of Pb2+ without Removal of Oxygen Analytical Chemistry. ,vol. 69, pp. 4660- 4664 ,(1997) , 10.1021/AC970420F
Nagahiro Hoshi, Makiko Kato, Yoshio Hori, Electrochemical reduction of CO2 on single crystal electrodes of silver Ag(111), Ag(100) and Ag(110) Journal of Electroanalytical Chemistry. ,vol. 440, pp. 283- 286 ,(1997) , 10.1016/S0022-0728(97)00447-6
D.A.J. Rand, R. Woods, A study of the dissolution of platinum, palladium, rhodium and gold electrodes in 1 m sulphuric acid by cyclic voltammetry Journal of Electroanalytical Chemistry. ,vol. 35, pp. 209- 218 ,(1972) , 10.1016/S0022-0728(72)80308-5
Grégoire Herzog, Damien W.M. Arrigan, Determination of trace metals by underpotential deposition–stripping voltammetry at solid electrodes Trends in Analytical Chemistry. ,vol. 24, pp. 208- 217 ,(2005) , 10.1016/J.TRAC.2004.11.014