Microwave-induced high surface functionalization of multi-walled carbon nanotubes for long-term dispersion in water
作者： M. Davarpanah , M. Maghrebi , E. Hosseinipour
DOI: 10.1007/S00339-013-7897-7
关键词: Chemical engineering 、 Diethanolamine 、 Raman spectroscopy 、 Materials science 、 Organic chemistry 、 Fourier transform infrared spectroscopy 、 Surface modification 、 Thermogravimetric analysis 、 Carbon nanotube 、 Triethanolamine 、 Spectroscopy
摘要: Multi-walled carbon nanotubes (MWCNTs) were functionalized by monoethanolamine (MEA), diethanolamine (DEA) and triethanolamine (TEA) a rapid microwave-assisted method. Surface functional groups morphology of MWCNTs analyzed ultraviolet-visible spectroscopy, Fourier transform infrared thermogravimetric analysis, Raman spectroscopy transmission electron microscopy. The water dispersibility samples was also measured over time compared with that MWCNT ethylenediamine (EDA). Accordingly, the in sequence MEA-MWCNTs > DEA-MWCNTs > TEA-MWCNTs > EDA-MWCNTs > pristine MWCNTs. significant long-term MEA-MWCNTs related to its exceptionally high surface functionalization (89.3 %) lack chemical bridging between adjacent This strategy, along low-cost functionalizing agents, could pave way for large-scale dispersion CNTs polar solvents.
springer.com
um.ac.ir
sci-hub.se 参考文章(32)
Heriberto Espinoza-Gómez, Gabriel Alonso-Nuñez, Ratnasamy Somanathan, Eduardo Rogel-Hernández, Eduardo Rogel-Hernández, Francisco Paraguay-Delgado, Gerardo Aguirre, Juan P. Camarena, Juan P. Camarena, Side-Wall Functionalization of Multi-Walled Carbon Nanotubes with t-Butyl Diazoacetate Revista de la Sociedad Química de Mexico. ,vol. 55, pp. 7- 10 ,(2011)
Kai Yang, Mingyuan Gu, Yiping Guo, Xifeng Pan, Guohong Mu, Effects of carbon nanotube functionalization on the mechanical and thermal properties of epoxy composites Carbon. ,vol. 47, pp. 1723- 1737 ,(2009) , 10.1016/J.CARBON.2009.02.029
Marianna Foldvari, Mukasa Bagonluri, Carbon nanotubes as functional excipients for nanomedicines: II. Drug delivery and biocompatibility issues Nanomedicine: Nanotechnology, Biology and Medicine. ,vol. 4, pp. 183- 200 ,(2008) , 10.1016/J.NANO.2008.04.003
Rodney S. Ruoff, Donald C. Lorents, Mechanical and thermal properties of carbon nanotubes Carbon. ,vol. 33, pp. 925- 930 ,(1995) , 10.1016/0008-6223(95)00021-5
Yingkui Yang, Shengqiang Qiu, Chengen He, Wenjie He, Linjuan Yu, Xiaolin Xie, Green chemical functionalization of multiwalled carbon nanotubes with poly(ɛ-caprolactone) in ionic liquids Applied Surface Science. ,vol. 257, pp. 1010- 1014 ,(2010) , 10.1016/J.APSUSC.2010.08.009
Hadi Zare Zardini, Ahmad Amiri, Mehdi Shanbedi, Morteza Maghrebi, Majid Baniadam, Enhanced antibacterial activity of amino acids-functionalized multi walled carbon nanotubes by a simple method Colloids and Surfaces B: Biointerfaces. ,vol. 92, pp. 196- 202 ,(2012) , 10.1016/J.COLSURFB.2011.11.045
Ester Vázquez, Maurizio Prato, Carbon Nanotubes and Microwaves: Interactions, Responses, and Applications ACS Nano. ,vol. 3, pp. 3819- 3824 ,(2009) , 10.1021/NN901604J
Rong Tian, Xianbao Wang, Mingjian Li, Huating Hu, Rong Chen, Fangming Liu, Han Zheng, Li Wan, An efficient route to functionalize singe-walled carbon nanotubes using alcohols Applied Surface Science. ,vol. 255, pp. 3294- 3299 ,(2008) , 10.1016/J.APSUSC.2008.09.040
Matteo D’Este, Marco De Nardi, Enzo Menna, A Co‐Functionalization Approach to Soluble and Functional Single‐Walled Carbon Nanotubes European Journal of Organic Chemistry. ,vol. 2006, pp. 2517- 2522 ,(2006) , 10.1002/EJOC.200600196
Christopher A. Dyke, James M. Tour, Overcoming the Insolubility of Carbon Nanotubes Through High Degrees of Sidewall Functionalization Chemistry: A European Journal. ,vol. 10, pp. 812- 817 ,(2004) , 10.1002/CHEM.200305534