Two Photoluminescent Metal–Organic Frameworks Constructed from Cd3(μ3‐OH) Cluster or 1D Zn5(μ3‐OH)2(μ‐OH)2 Chain Units and In Situ Formed Bis(tetrazole)amine Ligands
作者： Ling-Ling Zheng , Hao-Xiang Li , Ji-Dong Leng , Jing Wang , Ming-Liang Tong
关键词: Amine gas treating 、 Polymer chemistry 、 Zinc 、 Inorganic chemistry 、 Chemistry 、 Dicyanamide 、 Metal-organic framework 、 Microporous material 、 Sodium 、 Sodium azide 、 Tetrazole
摘要: Hydrothermal reactions of CdCl2·2.5H2O or ZnCl2, sodium dicyanamide, and azide yield two interesting photoluminescent coordination polymers, namely, [Cd{Cd3(μ3-OH)(dcadtzH)3(H2O)6}2] (1) [Zn5(μ3-OH)2(μ-OH)2(dcadtz)2]·2H2O (2) [dcadtzH3 = bis(5-tetrazolyl)amine], in which triangular [Cd3(μ3-OH)]5+ cluster subunits 1 1D [Zn5(μ3-OH)2(μ-OH)2]n6n+ chain 2 are linked by situ generated bis(tetrazole)amine ligands to generate an 2D net a 3D microporous metal–organic framework, respectively. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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