DOM removal by flocculation process: Fluorescence excitation–emission matrix spectroscopy (EEMs) characterization

作者: Guocheng Zhu , Jun Yin , Peng Zhang , Xiaofeng Wang , Gongduan Fan

DOI: 10.1016/J.DESAL.2014.04.031

关键词: Environmental chemistryFluorescenceFlocculationOrganic compoundChemistryMatrix (chemical analysis)Fluorescence spectroscopyWater treatmentSpectroscopyScientific methodChromatography

摘要: Abstract DOM is often utilized as a control parameter in the design of water treatment process well others such efficiency and formation disinfection byproducts (DBPs), which removal characterization have received wide attention. Fluorescence excitation–emission matrix spectroscopy (EEMs) for flocculation at present not known. It this reason that EEMs study was employed to characterize Missouri River by process. The results showed four underlying components extracted from parallel factor (PARAFAC) were humic acid-like (A), fulvic (B), protein-like (C) unidentified component (D), while dominated A, B C. Flocculation effective hydrophobic organic compound A followed hydrophilic compounds C, whereas smallest molecular size C hard treat. Further illustrated pH 7, higher DOC THM efficiencies obtained, correlations with significant, thus indicating EEMs-PARAFAC offers robust analytical method assessing

参考文章(56)
Colin A. Stedmon, Rasmus Bro, Characterizing dissolved organic matter fluorescence with parallel factor analysis: a tutorial Limnology and Oceanography: Methods. ,vol. 6, pp. 572- 579 ,(2008) , 10.4319/LOM.2008.6.572B
John Bridgeman, Magdalena Bieroza, Andy Baker, The application of fluorescence spectroscopy to organic matter characterisation in drinking water treatment Reviews in Environmental Science and Bio\/technology. ,vol. 10, pp. 277- 290 ,(2011) , 10.1007/S11157-011-9243-X
George R. Aiken, Heileen Hsu-Kim, Joseph N. Ryan, Influence of Dissolved Organic Matter on the Environmental Fate of Metals, Nanoparticles, and Colloids Environmental Science & Technology. ,vol. 45, pp. 3196- 3201 ,(2011) , 10.1021/ES103992S
Namguk Her, Gary Amy, Diane McKnight, Jinsik Sohn, Yeomin Yoon, Characterization of DOM as a function of MW by fluorescence EEM and HPLC-SEC using UVA, DOC, and fluorescence detection. Water Research. ,vol. 37, pp. 4295- 4303 ,(2003) , 10.1016/S0043-1354(03)00317-8
Huarong Yu, Fangshu Qu, Heng Liang, Zheng-shuang Han, Jun Ma, Senlin Shao, Haiqing Chang, Guibai Li, None, Understanding ultrafiltration membrane fouling by extracellular organic matter of Microcystis aeruginosa using fluorescence excitation-emission matrix coupled with parallel factor analysis Desalination. ,vol. 337, pp. 67- 75 ,(2014) , 10.1016/J.DESAL.2014.01.014
Colin A. Stedmon, Bożena Seredyńska-Sobecka, Rasmus Boe-Hansen, Nicolas Le Tallec, Christopher K. Waul, Erik Arvin, A potential approach for monitoring drinking water quality from groundwater systems using organic matter fluorescence as an early warning for contamination events. Water Research. ,vol. 45, pp. 6030- 6038 ,(2011) , 10.1016/J.WATRES.2011.08.066
Jerry A. Leenheer, Jean-Philippe Croué, Peer Reviewed: Characterizing Aquatic Dissolved Organic Matter Environmental Science & Technology. ,vol. 37, ,(2003) , 10.1021/ES032333C