Photocatalytic selective oxidation of methanol to methyl formate in gas phase over titanium(IV) oxide in a flow-type reactor
作者： Hiroshi Kominami , Hiroshi Sugahara , Keiji Hashimoto
DOI: 10.1016/J.CATCOM.2009.11.014
关键词: Titanium 、 Selectivity 、 Methanol 、 Photocatalysis 、 Oxide 、 Inorganic chemistry 、 Catalysis 、 Methyl formate 、 Deposition (phase transition) 、 Chemistry
摘要: Abstract Photocatalytic oxidation of methanol in air over titanium(IV) oxide particles having a large surface area 120 m 2 g −1 using flow-type reactor at room temperature yielded methyl formate with high level selectivity (91 mol%) without catalyst deactivation due to deposition intermediate(s). The conversion increased elevation the reaction up 523 K maintaining selectivity.
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