Thermal Reaction of Aluminum Alkoxide in Glycols
作者： Masashi Inoue , Hiroshi Kominami , Tomoyuki Inui
DOI: 10.1111/J.1151-2916.1990.TB05164.X
关键词: Inorganic chemistry 、 Heterolysis 、 Crystallite 、 Materials science 、 Aluminium 、 Thermal decomposition 、 Texture (crystalline) 、 Alkoxide 、 Boehmite 、 Polymer chemistry 、 Calcination
摘要: Thermal reaction of aluminum isopropoxide in glycols at 300°C yielded the glycol derivatives boehmite. The physical properties products and aluminas obtained by calcination strongly depended on crystallite size boehmite derivatives, which seems to be controlled heterolytic cleavage C-O bond HO(CH2)nOAI = formed alkoxide exchange between glycol. product had a unique honeycomb texture, was preserved form transition alumina.
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