Site-selective spectroscopy and crystallographic sites of Eu3+ ions doped in Gd2BaZnO5

作者: Yanlin Huang , Liang Shi , Eun Sik Kim , Hyo Jin Seo

DOI: 10.1063/1.3056167

关键词: LuminescenceCrystal structurePhotochemistryEmission spectrumExcited statePhotoluminescenceSpectroscopyStark effectIonChemistryCrystallography

摘要: The influence of the cationic sites on luminescent properties Eu3+ in Gd2BaZnO5 has been investigated by site-selective laser excitation and emission spectroscopy along with luminescence decays. It revealed that ions occupy two sites. Stark energy levels at different were assigned from selectively excited spectra 10 K. transfer between crystallographic centers is detected discussed. Excitation spectrum UV region UV-excited also performed, which indicate an efficient transfers host directly Gd3+ to Gd2BaZnO5.

参考文章(18)
Structure of Y2BaCuO5 Acta Crystallographica Section C-crystal Structure Communications. ,vol. 44, pp. 3- 6 ,(1988) , 10.1107/S0108270187008801
C. Michel, L. Er-Rakho, B. Raveau, Une nouvelle famille structurale: Les oxydes Ln4−2xBa2+2xZn2−xO10−2x (Ln = La, Nd) Journal of Solid State Chemistry. ,vol. 42, pp. 176- 182 ,(1982) , 10.1016/0022-4596(82)90265-1
G.K Cruz, H.C Basso, M.C Terrile, R.A Carvalho, Spectroscopic properties of Y2BaZnO5: Er3 + Journal of Luminescence. ,vol. 86, pp. 155- 160 ,(2000) , 10.1016/S0022-2313(99)00198-2
C. Michel, B. Raveau, Les oxydes A2BaCuO5 (A = Y, Sm, Eu, Gd, Dy, Ho, Er, Yb) Journal of Solid State Chemistry. ,vol. 43, pp. 73- 80 ,(1982) , 10.1016/0022-4596(82)90216-X
C. Michel, B. Raveau, Ln2BaZnO5 and Ln2BaZn1−xCuxO5: A series of zinc oxides with zinc in a pyramidal coordination Journal of Solid State Chemistry. ,vol. 49, pp. 150- 156 ,(1983) , 10.1016/0022-4596(83)90108-1
M.J.J. Lammers, H. Donker, G. Blasse, The luminescence of Eu3+, Tb3+ and Tm3+ activated Gd2BaZnO5 and La2BaZnO5 Materials Chemistry and Physics. ,vol. 13, pp. 527- 539 ,(1985) , 10.1016/0254-0584(85)90003-3
Riadh Ternane, Mokhtar Ferid, Gérard Panczer, Malika Trabelsi-Ayadi, Georges Boulon, Site-selective spectroscopy of Eu3+-doped orthorhombic lanthanum and monoclinic yttrium polyphosphates Optical Materials. ,vol. 27, pp. 1832- 1838 ,(2005) , 10.1016/J.OPTMAT.2004.11.005
J. A. Kaduk, W. Wong-Ng, G. Greenwood, J. Dillingham, B. H. Toby, Crystal Structures and Reference Powder Patterns of BaR 2 ZnO 5 (R=La,Nd,Sm,Eu,Gd,Dy,Ho,Y,Er, and Tm). Journal of Research of the National Institute of Standards and Technology. ,vol. 104, pp. 147- 171 ,(1999) , 10.6028/JRES.104.011