Generation of (nonafluoro-tert-butoxy)methyl ponytails for enhanced fluorous partition of aromatics and heterocycles
作者： Xi Zhao , Wing Yan Ng , Kai-Chung Lau , Alana E. C. Collis , István T. Horváth
DOI: 10.1039/C2CP23113A
关键词: Partition (number theory) 、 Solubility 、 Chemistry 、 Sodium 、 Tert-butoxy 、 Organic chemistry
摘要: The reaction of sodium perfluoro-tert-butoxide with benzylic carbon–bromide bond(s) leads to the formation (nonafluoro-tert-butoxy)methyl ponytail(s), which can enhance fluorous solubility and partition aromatics heterocycles.
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