Development of sustainable fluorous chemistry: the synthesis and characterization of fluorous ethers with nonafluoro-tert-butoxy groups
作者： Margaret B. Murphy , István T. Horváth , See-Wing Lo , Edwin Law , Matthew Y. Lui
DOI: 10.1039/C4QO00192C
关键词:
摘要: Nonafluoro-t-butyl propyl (1), allyl (2), and propargyl (3) ethers as well 1,2-bis(nonafluoro-t-butoxy)ethane (4), 1,3-bis(nonafluoro-t-butoxy)-propane (5), 1,4-bis(nonafluoro-t-butoxy)-butane (6) were prepared by the reaction of sodium nonafluoro-t-butoxide (7) with corresponding alkyl halides in good yields. Their fluorous partition coefficients toxicity also investigated. Computational studies have shown that 4, 5 6 exist a monomeric form MeOH–CF3C6F11 they likely aggregate to oligomers PhCH3–CF3C6F11.
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