How the Horváth paradigm, Fluorous Biphasic Catalysis, affected oxidation chemistry: Successes, challenges, and a sustainable future
作者： Jean-Marc Vincent , Maria Contel , Gianluca Pozzi , Richard H. Fish
DOI: 10.1016/J.CCR.2018.11.004
关键词:
摘要: Abstract Fluorous Biphasic Catalysis (FBC) has been a more than two decades old concept, that constituted paradigm shift in bi and triphasic homogeneous catalysis reactions. FBC expanded over the years to include variety of conceptually innovative strategies, enabling quick separation recovery suitable precatalysts, from substrates products. An overview development selective oxidation reactions, including allylic oxidation, peroxidation, epoxidation alkenes, primary secondary alcohols carbonyl compounds, is presented, with major focus on authors’ contributions field, showcasing principles fluorous precatalyst design, potential its many variants.
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