TiO2/SiO2 supported vanadia catalysts for the ODH of propane
作者： Soumik Chakraborty , Sudhir C. Nayak , Goutam Deo
DOI: 10.1016/J.CATTOD.2015.01.047
关键词: Catalysis 、 Monolayer 、 Propane 、 Dehydrogenation 、 Inorganic chemistry 、 Fourier transform infrared spectroscopy 、 Selectivity 、 Selective catalyst 、 Raman spectroscopy 、 Chemistry
摘要: Abstract Supported vanadia catalysts were prepared on two TiO 2 /SiO supports, which contained 70% and 90% . The supports thermally stable up to 1023 K surface species formed them. supported characterized by Raman FTIR spectroscopy, XRD TPR. area of the was also determined. active for propane oxidative dehydrogenation (ODH) reaction most selective catalyst 6% vanadia, appeared be monolayer limit these supports. Furthermore, with in support more than containing kinetic parameters determined able explain variations conversion at iso-contact time selectivity iso-conversion different catalysts.
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