Catalytic activity of supra molecular self-assembled Nickel (II) coordination complex in synthesis of indeno-pyrimidine derivatives

摘要: Abstract A supra molecular self-assembled Ni(II) coordination complex, formulated as [Ni2(2,6-pydc)2(μ-4,4′bpy)(H2O)4].2H2O (2,6-pydc: pyridine-2,6-dicarboxylic acid, 4,4′bpy:4,4′-bipyridine) was synthesized under hydrothermal condition and characterized by single crystal X-ray diffraction, elemental analysis, FT-IR, powder diffraction thermo gravimetric analysis. Single analysis reveals that the complex crystallizes in monoclinic space group P21/c with cell parameters a = 10.5237(6) A, b = 20.1966(10) A, c = 7.2366(4) A, β = 106.96(1°), V = 1471.22(314) A3 displays a 3D supramolecular network through hydrogen bond C–H⋯π, C–O⋯π interactions. Nickel(II) metal species structure possess coordinately unsaturated centers, which exhibited viable catalytic properties synthesis of five different indeno-pyrimidine derivatives one-pot reaction involving aldehyde, indane-1,3-dione guanidinium chloride green approach. With achieved 15 min time interval ethanol excellent yields (87–98%), plus good recyclability (up to 6 times) provides advantage this heterogeneous catalysis.