Synthesis, characterization and experimental, theoretical, electrochemical, antioxidant and antibacterial study of a new Schiff base and its complexes.
作者： Haci Baykara , Salih Ilhan , Abdulkadir Levent , M. Salih Seyitoglu , Sadin Özdemir
DOI: 10.1016/J.SAA.2014.03.094
关键词: Inorganic chemistry 、 Biphenyl compound 、 Octahedron 、 Molar conductivity 、 Crystallography 、 Cyclic voltammetry 、 Salicylaldehyde 、 Schiff base 、 Tetrahedral molecular geometry 、 Chemistry 、 Ligand
摘要: A new Schiff base ligand was synthesized by reaction of salicylaldehyde with 1,6-bis(4-chloro-2-aminophenoxy)hexane. Then the complexes were metal salts and base. The to ratio found be 1:1. Cu(II) complex is proposed square planar Co(II), Ni(II), Mn(II) Zn(II) are tetrahedral geometry. Ti(III) V(III) a capped octahedron in which seventh has been added triangular face. non-electrolytes as shown their molar conductivities (ΛM). structure from elemental analysis, FT-IR, UV-vis, magnetic susceptibility measurements, conductivity Mass Spectra thermal gravimetric analysis. In addition antimicrobial antioxidant studies, cyclic voltammetry complexes, theoretical 1H NMR HOMO-LUMO energy calculations di-functional done.
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sci-hub.se 参考文章(63)
Alan Earnshaw, Introduction to Magnetochemistry ,(1968)
James B. Foresman, Æleen Frisch, Exploring chemistry with electronic structure methods ,(1993)
Gajendra Kumar, Shoma Devi, Rajeev Johari, Dharmendra Kumar, Synthesis, spectral characterization and antimicrobial evaluation of Schiff base Cr (III), Mn (III) and Fe (III) macrocyclic complexes. European Journal of Medicinal Chemistry. ,vol. 52, pp. 269- 274 ,(2012) , 10.1016/J.EJMECH.2012.03.025
Abdalla M. Khedr, M. Gaber, Hatem A. Diab, Synthesis, characterization, molecular modeling, and thermal analyses of bioactive Co(II) and Cu(II) complexes with diacetylmonoxime and different amines Journal of Coordination Chemistry. ,vol. 65, pp. 1672- 1684 ,(2012) , 10.1080/00958972.2012.678338
Kenichi Oyaizu, Eishun Tsuchida, Crystal structure and reactivity of a five-coordinate chloroiron(III) complex with a bulky tetradentate Schiff base ligand Inorganica Chimica Acta. ,vol. 355, pp. 414- 419 ,(2003) , 10.1016/S0020-1693(03)00311-6
V. Balachandran, A. Nataraj, T. Karthick, Molecular structure, spectroscopic (FT-IR, FT-Raman) studies and first-order molecular hyperpolarizabilities, HOMO-LUMO, NBO analysis of 2-hydroxy-p-toluic acid. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 104, pp. 114- 129 ,(2013) , 10.1016/J.SAA.2012.11.052
Katsuhiko Miyoshi, Jun Wang, Tsutomu Mizuta, None, An X-ray crystallographic study on the molecular structures of seven-coordinate (ethylenediamine-N,N,N′-triacetato-N′-acetic acid) (aqua) -titanium(III) and -vanadium(III), [TiIII(H-edta)(H2O)]·H2O and [VIII(Hedta)(H2O)]·H2O Inorganica Chimica Acta. ,vol. 228, pp. 165- 172 ,(1995) , 10.1016/0020-1693(94)04163-P
B Shivarama Holla, B Veerendra, M.K Shivananda, Boja Poojary, Synthesis characterization and anticancer activity studies on some Mannich bases derived from 1,2,4-triazoles. European Journal of Medicinal Chemistry. ,vol. 38, pp. 759- 767 ,(2003) , 10.1016/S0223-5234(03)00128-4
Sushil K. Gupta, Chanda Anjana, Neha Sen, Ray J. Butcher, Jerry P. Jasinski, Synthesis, crystal structure, DFT and spectroscopic studies of mononuclear chromium(III) complex with bidentate ligand Polyhedron. ,vol. 43, pp. 8- 14 ,(2012) , 10.1016/J.POLY.2012.05.017
M. Salih Ağırtaş, Metin Çelebi, Selçuk Gümüş, Sadin Özdemir, Veysi Okumuş, New water soluble phenoxy phenyl diazenyl benzoic acid substituted phthalocyanine derivatives: Synthesis, antioxidant activities, atypical aggregation behavior and electronic properties Dyes and Pigments. ,vol. 99, pp. 423- 431 ,(2013) , 10.1016/J.DYEPIG.2013.05.019