Side-chain functionalized liquid crystalline polymers and blends, 10: phase behavior and structure of side-chain liquid crystalline ionomers containing ions of d-metals
作者： E.B Barmatov , D.A Pebalk , M.V Barmatova , V.P Shibaev
DOI: 10.1016/S0032-3861(02)00057-5
关键词: Ionomer 、 Metal ions in aqueous solution 、 Mesogen 、 Phase (matter) 、 Mesophase 、 Polymer 、 Polymer chemistry 、 Materials science 、 Liquid crystal 、 Side chain
摘要: Abstract Novel side-chain liquid crystalline (LC) ionomers containing d-metals Co(II) and Ni(II) were synthesized characterized. Both families of the are characterized by same influence charged group content in polymer on their phase behavior. The incorporation 2–3 mol% metal ions nematic matrix leads to induction SmA rise clearing point. peculiarity behavior comparison with earlier investigated LC alkaline or alkali-earth metals is full destruction mesophase at concentration d-metal higher than 12 mol%. This phenomenon was associated well-known ability transition form various complexes that, case ionomers, can negatively ordering side mesogenic groups. proposed structure discussed metallomesogenic systems.
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sci-hub.se 参考文章(19)
Edward A. Boudreaux, L. N. Mulay, Theory and applications of molecular diamagnetism ,(1976)
F. Albert Cotton, Advanced Inorganic Chemistry ,(1999)
Günter Schnurpfeil, Dieter Wöhrle, Macromolecule-Metal Complexes ,(2012)
José Luis Serrano, Metallomesogens : synthesis, properties, and applications VCH. ,(1996)
Amadeus Wiesemann, Rudolf Zentel, Tadeusz Pakula, Redox-active liquid-crystalline ionomers: 1. Synthesis and rheology Polymer. ,vol. 33, pp. 5315- 5320 ,(1992) , 10.1016/0032-3861(92)90818-H
Matthias Paßmann, Götz Wilbert, Didier Cochin, Rudolf Zentel, Nematic ionomers as materials for the build-up of multilayers Macromolecular Chemistry and Physics. ,vol. 199, pp. 179- 189 ,(1998) , 10.1002/(SICI)1521-3935(19980201)199:2<179::AID-MACP179>3.0.CO;2-U
A. Eisenberg, B. Hird, R. B. Moore, A new multiplet-cluster model for the morphology of random ionomers Macromolecules. ,vol. 23, pp. 4098- 4107 ,(1990) , 10.1021/MA00220A012
Huanli Lei, Yue Zhao, An easy way of preparing side-chain liquid crystalline ionomers Polymer Bulletin. ,vol. 31, pp. 645- 649 ,(1993) , 10.1007/BF00300122
Yue Zhao, Huanli Lei, Side-Chain Liquid Crystalline Ionomers. 1. Preparation through Alkaline Hydrolysis and Characterization Macromolecules. ,vol. 27, pp. 4525- 4529 ,(1994) , 10.1021/MA00094A015
Evgueni Barmatov, Dmitry Pebalk, Marina Barmatova, Valery Shibaev, Side‐chain functionalized liquid crystalline polymers and blends, 2. Phase behavior of comb‐shaped liquid crystalline ionomers containing ions of alkaline metals Macromolecular Rapid Communications. ,vol. 21, pp. 369- 374 ,(2000) , 10.1002/(SICI)1521-3927(20000401)21:7<369::AID-MARC369>3.0.CO;2-O