Investigation of a long-lived intermediate in the photo-oxidation of chlorocuprate(I) complexes
作者： Ottó Horváth , Sándor Papp
DOI: 10.1016/0047-2670(85)85089-9
关键词: Photochemistry 、 Chemistry 、 Polymer 、 Quantum yield 、 Dimer 、 Kinetics 、 Ultraviolet radiation
摘要: Abstract The decay of a long-lived intermediate formed in the photo-oxidation acidic solutions chlorocuprate(I) complexes was examined. dependences rate on components this system (Cu I , Cu II Cl − andH + ) confirmed assumptions that dimeric or polymeric -Cu chloro are during photo-oxidation. quantum yield obtained indirectly as well estimate for concentration were accordance with results from previous experiments.
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