Individual quantum yields of Fe3+(HCO2−n complexes (n = 1 – 4) in aqueous acidic solutions

作者: L. Vincze , S. Papp

DOI: 10.1016/0047-2670(87)80019-9

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摘要: Abstract The following molar absorbancies and individual quantum yields (IQYs) of iron(III)—formate complexes were determined at a wavelength 254 nm: ϵ(Fe 3+ HCO 2 − ) = 4080 ± 320 M −1 cm ; ϵ{Fe (HCO } 3440 170 3 (2 × 10 4 5040 130 Φ(Fe 0.9 0.1; Φ{Fe 0.31 0.06; 0.15 0.38 0.02. A detailed computation procedure for the determination IQYs kinetically labile is discussed.

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