The chemistry of technetium (V)

作者: Alan Davison , Alun G. Jones

DOI: 10.1016/0020-708X(82)90131-4

关键词: StereochemistryReactivity (chemistry)TechnetiumMoleculeCrystallographyChemistry

摘要: Abstract The synthesis, reactivity and molecular structure of a variety technetium(V) completes are reviewed. oxotechnetium(V) species most conveniently categorized on the basis their oxotechnetium cores (a) TcO 3+ ; (b) trans -TcO 2 + (c) linear Tc O 3 4+ . All contain terminal Tc=O bond, spin-paired diamagnetic compounds.

参考文章(32)
James E. Smith, E. F. Byrne, F. Albert Cotton, Janine C. Sekutowski, A thiol complex of technetium pertinent to radiopharmaceutical use of technetium-99m Journal of the American Chemical Society. ,vol. 100, pp. 5571- 5572 ,(1978) , 10.1021/JA00485A057
Chris Orvig, Harvey S. Trop, Alan Davison, Michael A. Davis, Alun G. Jones, A survey of reducing agents for the synthesis of tetraphenylarsonium oxotechnetiumbis(ethanedithiolate) from [99Tc] pertechnetate in aqueous solution. The Journal of Nuclear Medicine. ,vol. 21, pp. 279- 281 ,(1980)
Rudy W. Thomas, Gregory W. Estes, R. C. Elder, Edward Deutsch, Technetium radiopharmaceutical development. 1. Synthesis, characterization, and structure of dichloro[hydrotris(1-pyrazolyl)borato]oxotechnetium(V) Journal of the American Chemical Society. ,vol. 101, pp. 4581- 4585 ,(1979) , 10.1021/JA00510A024
A. J. EDWARDS, D. HUGILL, R. D. PEACOCK, NEW FLUORINE COMPOUNDS OF TECHNETIUM Nature. ,vol. 200, pp. 672- 672 ,(1963) , 10.1038/200672A0
J. Steigman, G. Meinken, P. Richards, The reduction of pertechnetate-99 by stannous chloride—I. The stoichiometry of the reaction in HCl, in a citrate buffer and in a DTPA buffer The International Journal of Applied Radiation and Isotopes. ,vol. 26, pp. 601- 609 ,(1975) , 10.1016/0020-708X(75)90078-2
Bary W. Wilson, C. E. Costello, S. A. Carr, K. Biemann, Chris Orvig, A. Davison, A. G. Jones, Field desorption mass spectrometry of complex anions containing rhenium and technetium Analytical Letters. ,vol. 12, pp. 303- 311 ,(1979) , 10.1080/00032717908082533
Henry Taube, Rates and Mechanisms of Substitution in Inorganic Complexes in Solution. Chemical Reviews. ,vol. 50, pp. 69- 126 ,(1952) , 10.1021/CR60155A003
R. Kent Murmann, ReO4--H2O exchange kinetics in methanol using oxygen-18 Journal of the American Chemical Society. ,vol. 93, pp. 4184- 4186 ,(1971) , 10.1021/JA00746A015
Hartmut Spies, Bernd Johannsen, Oxotechnetium(V)bis(dithiolato) complexes Inorganica Chimica Acta. ,vol. 48, pp. 255- 258 ,(1981) , 10.1016/S0020-1693(00)90099-9
George Rouschias, Recent advances in the chemistry of rhenium Chemical Reviews. ,vol. 74, pp. 531- 566 ,(1974) , 10.1021/CR60291A002