Electronic and Nuclear Relaxation Of Core-Excited Molecules

作者: Irène Nenner , Paul Morin

DOI: 10.1007/978-1-4613-0315-2_9

关键词: Chemical bondValence electronMaterials scienceElectron energy loss spectroscopyMoleculeIonizationDissociation (chemistry)Coulomb explosionDouble ionizationMolecular physics

摘要: Ionization and dissociation of core-excited molecules is a subject intimately related to the problem relaxation inner vacancy coupling nuclear motion. For built with light atoms, Auger decay rate dominates largely x-ray fluorescence so we will concentrate on effect ejection several electrons through Auger-like processes. In contrast which are stripped outer valence core excitation, lose their integrity efficiently destroyed because many form cement chemical bonds removed. other words, efficiency, defined as number broken over total in original molecule, high may reach unity (a full “atomization” system) for small or medium size.

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