Verfahren zur Wasserspaltung
作者： Carl-Jochen Winter , Joachim Nitsch
DOI: 10.1007/978-3-642-97884-5_8
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摘要: Zweckmasigerweise unterscheidet man die konventionellen chemischen Verfahren der Wasserspaltung von elektrolytischen und mittels thermischer Kreis- Hybridprozesse. Wasserstoffgewinnung durch chemische Wasser Spaltung basiert in Prozestechnik auf Redoxreaktionen, denen letzten Endes mit Kohlenstoff oder Kohlenmono-xid reagiert. Wohl das alteste derartige ist Wasserdampf metallisches Eisen [7.1]: $$ % MathType!MTEF!2!1!+- feaagCart1ev2aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9 vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaaeaaaaaaaaa8 qacaqGibWdamaaBaaaleaapeGaaeOmaaWdaeqaaOWdbiaab+eacaqG RaGaaeOraiaabwgacqGHsgIRcaqGgbGaaeyzaiaab+eacaqGRaGaae isa8aadaWgaaWcbaWdbiaaikdaa8aabeaak8qacqqHuoarcaWGibWd amaaCaaaleqabaWdbiaaicdaaaGccqGH9aqpcqGHsislcaaI5aGaai ilaiaaikdacaaIWaGaae4AaiaabQeacaqGVaGaaeyBaiaab+gacaqG SbGaaiilaaaa!505F! {{\text{H}}_{\text{2}}}{\text{O + Fe}} \to {\text{FeO }}{{\text{H}}_2}\Delta {H^0} = - 9,20{\text{kJ/mol}}, $$ (7.1)
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