XPS/SIMS studies of the promoter action in methanol synthesis over silica-supported Pd catalysts
作者： C. Sellmer , R. Prins , N. Kruse
关键词: Transition metal 、 Catalysis 、 Inorganic chemistry 、 Methanol 、 Chemistry 、 Formate 、 Secondary ion mass spectrometry 、 Mass spectrum 、 X-ray photoelectron spectroscopy 、 Carbon monoxide
摘要: Pd-based catalysts prepared from ultra-pure SiO2 and doped with 5000 ppm Li, Ca La were subjected to CO hydrogenation(H2/CO=2, p=9 bar, T=553 K) in a flow reactor directly attached an ultra-high vacuum chamber facilities for X-ray photoelectron spectroscopy (XPS) secondary ion mass spectrometry (SIMS). The exhibited high selectivity (usually above 99%) methanol synthesis their activities found increase the order Li
springer.com
ulb.ac.be
sci-hub.se 参考文章(22)
J DRIESSEN, On the selectivity of palladium catalysts in synthesis gas reactions Journal of Catalysis. ,vol. 82, pp. 26- 34 ,(1983) , 10.1016/0021-9517(83)90114-8
V. Pitchon, H. Praliaud, G.A. Martin, On the Role of Hydroxyl Groups in the CO Hydrogenation into Methanol on Alkali-Promoted Pd/SiO2 Catalysts Studies in Surface Science and Catalysis. ,vol. 61, pp. 265- 271 ,(1991) , 10.1016/S0167-2991(08)60090-7
A. Henrion, H. Ewald, H. Miessner, T. Zimmermann, Application of chemometric tools to catalysis : carbon monoxide hydrogenation on a multipromoted Rh/SiO2 catalyst Applied Catalysis. ,vol. 62, pp. 23- 34 ,(1990) , 10.1016/S0166-9834(00)82234-4
Yasuo Kikuzono, Setsuko Kagami, Shuichi Naito, Takaharu Onishi, Kenzi Tamaru, Selective hydrogenation of carbon monoxide on palladium catalysts Faraday Discussions of the Chemical Society. ,vol. 72, pp. 135- 143 ,(1981) , 10.1039/DC9817200135
C. Sellmer, A. Gaussmann, N. Kruse, R. Prins, High-pressure flow reactor designed for an ultrahigh vacuum analysis system Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. ,vol. 15, pp. 365- 368 ,(1997) , 10.1116/1.580492
A.M. Kazi, B. Chen, J.G. Goodwin, G. Marcelin, N. Rodriguez, T.K. Baker, Li+ Promotion of Pd/SiO2: The Effect on Hydrogenation, Hydrogenolysis, and Methanol Synthesis Journal of Catalysis. ,vol. 157, pp. 1- 13 ,(1995) , 10.1006/JCAT.1995.1262
M. Rebholz, N. Kruse, Mechanisms of methanol decomposition on Pd {111} Journal of Chemical Physics. ,vol. 95, pp. 7745- 7759 ,(1991) , 10.1063/1.461348
M POUTSMA, Selective formation of methanol from synthesis gas over palladium catalysts Journal of Catalysis. ,vol. 52, pp. 157- 168 ,(1978) , 10.1016/0021-9517(78)90131-8
Véronique Pitchon, Michelle Guenin, Hélène Praliaud*, X-ray photoelectron spectroscopic study of the electronic state of palladium in alkali metal doped Pd/SiO2 solids Applied Catalysis. ,vol. 63, pp. 333- 343 ,(1990) , 10.1016/S0166-9834(00)81723-6
Robert J. Levis, Jiang. Zhicheng, Nicholas. Winograd, Evidence for activation of the C-O bond of methanol on the Pd{111} surface after low-temperature adsorption Journal of the American Chemical Society. ,vol. 110, pp. 4431- 4432 ,(1988) , 10.1021/JA00221A063