Organometallic-Mediated Radical Polymerization of Vinylidene Fluoride.
作者： Sanjib Banerjee , Vincent Ladmiral , Antoine Debuigne , Christophe Detrembleur , Rinaldo Poli
关键词: Copolymer 、 Cobalt 、 Fluorinated polymer 、 One-pot synthesis 、 Polymer chemistry 、 Radical polymerization 、 Dispersity 、 Chemistry 、 Fluoride
摘要: An unprecedented level of control for the radical polymerization vinylidene fluoride (VDF), yielding well-defined PVDF (at least up to 14 500 g mol-1 ) with low dispersity (≤1.32), was achieved using organometallic-mediated (OMRP) an organocobalt compound as initiator. The high chain-end fidelity demonstrated by synthesis PVDF- and PVAc-containing di-and triblock copolymers. DFT calculations rationalize efficient reactivation both head tail chain end dormant species.
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Anthony Kermagoret, Antoine Debuigne, Christine Jérôme, Christophe Detrembleur, Precision design of ethylene- and polar-monomer-based copolymers by organometallic-mediated radical polymerization Nature Chemistry. ,vol. 6, pp. 179- 187 ,(2014) , 10.1038/NCHEM.1850
Wei Weng, Zhongliang Shen, Richard F. Jordan, Copolymerization of ethylene and vinyl fluoride by (phosphine-sulfonate)Pd(Me)(py) catalysts. Journal of the American Chemical Society. ,vol. 129, pp. 15450- 15451 ,(2007) , 10.1021/JA0774717
Mathias Destarac, Krzysztof Matyjaszewski, Eric Silverman, Bruno Ameduri, Bernard Boutevin, Atom Transfer Radical Polymerization Initiated with Vinylidene Fluoride Telomers Macromolecules. ,vol. 33, pp. 4613- 4615 ,(2000) , 10.1021/MA9918351
Zhaoliang Cui, Enrico Drioli, Young Moo Lee, Recent progress in fluoropolymers for membranes Progress in Polymer Science. ,vol. 39, pp. 164- 198 ,(2014) , 10.1016/J.PROGPOLYMSCI.2013.07.008
R. Liepins, J. R. Surles, N. Morosoff, V. T. Stannett, M. L. Timmons, J. J. Wortman, Poly(vinylidene fluoride) with low content of head‐to‐head chain imperfections Journal of Polymer Science Part A. ,vol. 16, pp. 3039- 3044 ,(1978) , 10.1002/POL.1978.170161135
Antoine Debuigne, Jean-Raphaël Caille, Robert Jérôme, Synthesis of End-Functional Poly(vinyl acetate) by Cobalt-Mediated Radical Polymerization Macromolecules. ,vol. 38, pp. 5452- 5458 ,(2005) , 10.1021/MA047726Q
Georgi Kostov, Frédéric Boschet, Jens Buller, Leila Badache, Stephan Brandsadter, Bruno Ameduri, First Amphiphilic Poly(vinylidene fluoride-co-3,3,3-^trifluoropropene)-b-oligo(vinyl alcohol) Block Copolymers as Potential Nonpersistent Fluorosurfactants from Radical Polymerization Controlled by Xanthate Macromolecules. ,vol. 44, pp. 1841- 1855 ,(2011) , 10.1021/MA102679F
Antoine Debuigne, Marie Hurtgen, Christophe Detrembleur, Christine Jérôme, Christopher Barner-Kowollik, Thomas Junkers, Interpolymer radical coupling: A toolbox complementary to controlled radical polymerization Progress in Polymer Science. ,vol. 37, pp. 1004- 1030 ,(2012) , 10.1016/J.PROGPOLYMSCI.2012.01.003
Bruno Ameduri, From vinylidene fluoride (VDF) to the applications of VDF-containing polymers and copolymers: recent developments and future trends. Chemical Reviews. ,vol. 109, pp. 6632- 6686 ,(2009) , 10.1021/CR800187M
Jamil Ahmad, May Britt Hågg, Polyvinyl acetate/titanium dioxide nanocomposite membranes for gas separation Journal of Membrane Science. ,vol. 445, pp. 200- 210 ,(2013) , 10.1016/J.MEMSCI.2013.04.052