Phase equilibrium for capsaicin+water+ethanol+supercritical carbon dioxide

作者: Catarina M.M Duarte , Marcelo Crew , Teresa Casimiro , Ana Aguiar-Ricardo , Manuel Nunes da Ponte

DOI: 10.1016/S0896-8446(01)00114-0

关键词: Extraction (chemistry)Vapor–liquid equilibriumNuclear chemistryMass fractionWater contentChemistryFraction (chemistry)ChromatographySupercritical fluid extractionEthanolSupercritical carbon dioxide

摘要: Abstract The possibility of extracting capsaicin with supercritical carbon dioxide from a hydroalcholic mixture containing the alkaloid was investigated. High-pressure phase equilibrium on quaternary system CO 2 +ethanol+water+capsaicin measured in order to obtain separation factor natural product hydro-alcoholic model mixtures. Experiments behavior were performed at several pressures (12, 15 and 18 MPa) temperatures 40 50 °C. factors for three mixtures different composition—0.40 water+0.60 ethanol mass fraction 0.9 water+0.10 fraction, 0.02% 0.40 water 0.04% capsaicin—are compared. effect content selectivity extraction process is discussed.

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