Satellite structure in the x‐ray photoelectron spectra of the K shell of transition metal compounds

作者: Thomas A. Carlson , James C. Carver , G. A. Vernon

DOI: 10.1063/1.430544

关键词: X-ray photoelectron spectroscopySpectral lineShakeSpectroscopyPhotoionizationElectron spectroscopyElectron shellAtomic physicsMultipletChemistry

摘要: Satellite structure has been measured in the x−ray photoelectron spectra for FeCl3, FeBr3, K3Fe(CN)6, and K4Fe(CN)6. Specifically, comparisons were made of satellites found 2p 1s subshells iron. To interpret data, calculations are presented on electron shake up off, multiplet splitting as a function location inner shell vacancy It is demonstrated, theoretically, that satellite photoionization K iron must be due to not splitting. From experimental data FeCl3 conclusion reached formed result primarily up.

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