作者: Thomas A. Carlson , James C. Carver , G. A. Vernon
DOI: 10.1063/1.430544
关键词: X-ray photoelectron spectroscopy 、 Spectral line 、 Shake 、 Spectroscopy 、 Photoionization 、 Electron spectroscopy 、 Electron shell 、 Atomic physics 、 Multiplet 、 Chemistry
摘要: Satellite structure has been measured in the x−ray photoelectron spectra for FeCl3, FeBr3, K3Fe(CN)6, and K4Fe(CN)6. Specifically, comparisons were made of satellites found 2p 1s subshells iron. To interpret data, calculations are presented on electron shake up off, multiplet splitting as a function location inner shell vacancy It is demonstrated, theoretically, that satellite photoionization K iron must be due to not splitting. From experimental data FeCl3 conclusion reached formed result primarily up.