Hydrothermal synthesis and electrochemical behavior of orthorhombic LiMnO2

作者: Seung-Taek Myung , Shinichi Komaba , Naoaki Kumagai

DOI: 10.1016/S0013-4686(02)00248-7

关键词: Inorganic chemistryLithium batteryLithium oxideHydrothermal circulationOxideOrthorhombic crystal systemCalcinationBattery (electricity)ChemistryHydrothermal synthesis

摘要: Abstract The most highlighted point of this work to emphasize is that it the first trial use Mn 3 O 4 oxide as a precursor synthesize orthorhombic LiMnO 2 by hydrothermal method. A well-ordered phase was formed treatment with excess LiOH aqueous solution at 170 °C. According TEM observation, as-synthesized powder single crystalline particle oxide. Comparing other prepared low temperature synthetic route and high calcination, showed enhanced battery performance lithium cathode material. We believe new synthesis expected an excellent alternative preparation method capacity material be used for Li-ion secondary battery.

参考文章(33)
W. D. Johnston, R. R. Heikes, A Study of the LixMn(1-x)O System1 Journal of the American Chemical Society. ,vol. 78, pp. 3255- 3260 ,(1956) , 10.1021/JA01595A006
J. M. Tarascon, D. Guyomard, Li Metal‐Free Rechargeable Batteries Based on Li1 + x Mn2 O 4 Cathodes ( 0 ≤ x ≤ 1 ) and Carbon Anodes Journal of The Electrochemical Society. ,vol. 138, pp. 2864- 2868 ,(1991) , 10.1149/1.2085331
I. M. Kötschau, J. R. Dahn, In Situ X‐Ray Study of LiMnO2 Journal of The Electrochemical Society. ,vol. 145, pp. 2672- 2677 ,(1998) , 10.1149/1.1838698
J. N. Reimers, Eric W. Fuller, Erik Rossen, J. R. Dahn, Synthesis and Electrochemical Studies of LiMnO2 Prepared at Low Temperatures Journal of The Electrochemical Society. ,vol. 140, pp. 3396- 3401 ,(1993) , 10.1149/1.2221101
J. M. Tarascon, E. Wang, F. K. Shokoohi, W. R. McKinnon, S. Colson, THE SPINEL PHASE OF LIMN2O4 AS A CATHODE IN SECONDARY LITHIUM CELLS Journal of The Electrochemical Society. ,vol. 138, pp. 2859- 2864 ,(1991) , 10.1149/1.2085330
Young‐Il Jang, Biying Huang, Haifeng Wang, Donald R. Sadoway, Yet‐Ming Chiang, Electrochemical Cycling‐Induced Spinel Formation in High‐Charge‐Capacity Orthorhombic LiMnO2 Journal of The Electrochemical Society. ,vol. 146, pp. 3217- 3223 ,(1999) , 10.1149/1.1392457
Mitsuharu Tabuchi, Kazuaki Ado, Christian Masquelier, Ichiro Matsubara, Hikari Sakaebe, Hiroyuki Kageyama, Hironori Kobayashi, Ryoji Kanno, Osamu Nakamura, Electrochemical and magnetic properties of lithium manganese oxide spinels prepared by oxidation at low temperature of hydrothermally obtained LiMnO2 Solid State Ionics. ,vol. 89, pp. 53- 63 ,(1996) , 10.1016/0167-2738(96)00273-1
M THOMAS, P BRUCE, J GOODENOUGH, Lithium mobility in the layered oxide Li1−xCoO2 Solid State Ionics. ,vol. 17, pp. 13- 19 ,(1985) , 10.1016/0167-2738(85)90117-1
Yoshiaki Nitta, Masatoshi Nagayama, Hajime Miyake, Akira Ohta, Synthesis and reaction mechanism of 3 V LiMnO2 Journal of Power Sources. ,vol. 81, pp. 49- 53 ,(1999) , 10.1016/S0378-7753(99)00102-0