Estimation of Li+ transport number in polymer electrolytes by the combination of complex impedance and potentiostatic polarization measurements
作者： Masayoshi Watanabe , Satoshi Nagano , Kohei Sanui , Naoya Ogata
DOI: 10.1016/0167-2738(88)90303-7
关键词: Electrolyte 、 Inorganic chemistry 、 Magazine 、 Polarization (electrochemistry) 、 Ionic conductivity 、 Polymer 、 Ethylene oxide 、 Chemical substance 、 Analytical chemistry 、 Materials science 、 Covalent bond
摘要: The Li+ transport numbers of two types of polymer electrolytes have been estimated by means of the combination of the complex impedance and potentiostatic polarization measurements. Type I electrolytes were the network polymers with dissolved LiClO 4 obtained from poly (ethylene oxide)(PEO) and from PEO-grafted-polydimethylsiloxane. Type II electrolyte was the network polymer obtained from PEO where-COO− Li+ groups were linked to the polymer backbone by covalent bonds. The ionic conductivity and Li+ transport …
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sci-hub.se 参考文章(10)
M. Watanabe, M. Rikukawa, K. Sanui, N. Ogata, Evaluation of ionic mobility and transference number in a polymeric solid electrolyte by isothermal transient ionic current method Journal of Applied Physics. ,vol. 58, pp. 736- 740 ,(1985) , 10.1063/1.336191
Masayoshi Watanabe, Makiko Togo, Kohei Sanui, Naoya Ogata, Tadahiko Kobayashi, Zentaro Ohtaki, Ionic conductivity of polymer complexes formed by poly(β-propiolactone) and lithium perchlorate Macromolecules. ,vol. 17, pp. 2908- 2912 ,(1984) , 10.1021/MA00142A079
Masayoshi Watanabe, Kohei Sanui, Naoya Ogata, Fumio Inoue, Tadahiko Kobayashi, Zentaro Ohtaki, Temperature Dependence of Ionic Conductivity of Crosslinked Poly(propylene oxide) Films Dissolving Lithium Salts and Their Interfacial Charge Transfer Resistance in Contact with Lithium Electrodes Polymer Journal. ,vol. 16, pp. 711- 716 ,(1984) , 10.1295/POLYMJ.16.711
Masayoshi Watanabe, Masahiro Rikukawa, Kohei Sanui, Naoya Ogata, Hisaaki Kato, Tadahiko Kobayashi, Zentaro Ohtaki, Ionic conductivity of polymer complexes formed by poly(ethylene succinate) and lithium perchlorate Macromolecules. ,vol. 17, pp. 2902- 2908 ,(1984) , 10.1021/MA00142A078
Masayoshi Watanabe, Satoshi Nagano, Kohei Sanui, Naoya Ogata, Ionic Conductivity of Network Polymers from Poly(ethylene oxide) Containing Lithium Perchlorate Polymer Journal. ,vol. 18, pp. 809- 817 ,(1986) , 10.1295/POLYMJ.18.809
M. Watanabe, S. Nagano, K. Sanui, N. Ogata, Structure-conductivity relationsihp in polymer electrolytes formed by network polymers from poly[dimethylsiloxane-g- poly(ethylene oxide)] and litegum perchlorate Journal of Power Sources. ,vol. 20, pp. 327- 332 ,(1987) , 10.1016/0378-7753(87)80131-3
N KOBAYASHI, M UCHIYAMA, E TSUCHIDA, Poly[lithium methacrylate-co-oligo(oxyethylene)methacrylate] as a solid electrolyte with high ionic conductivity Solid State Ionics. ,vol. 17, pp. 307- 311 ,(1985) , 10.1016/0167-2738(85)90075-X
Poul Ravn Sørensen, Torben Jacobsen, Conductivity, charge transfer and transport number—an ac-investigation of the polymer electrolyte LiSCN-poly(ethyleneoxide) Electrochimica Acta. ,vol. 27, pp. 1671- 1675 ,(1982) , 10.1016/0013-4686(82)80162-X
J. Ross Macdonald, Theory of space‐charge polarization and electrode‐discharge effects The Journal of Chemical Physics. ,vol. 58, pp. 4982- 5001 ,(1973) , 10.1063/1.1679086
J. Ross Macdonald, Simplified impedance/frequency‐response results for intrinsically conducting solids and liquids Journal of Chemical Physics. ,vol. 61, pp. 3977- 3996 ,(1974) , 10.1063/1.1681691