Study of molecular interactions in binary mixtures of formamide with 2-methoxyethanol and 2-ethoxyethanol at varying temperatures
作者： Rahul Singh , Maimoona Yasmin , Harshit Agarwal , Vivek Kumar Shukla , Manisha Gupta
DOI: 10.1080/00319104.2013.763941
关键词: 2-Methoxyethanol 、 Partial molar property 、 Thermodynamics 、 Viscosity 、 Molar volume 、 Volume (thermodynamics) 、 Chemistry 、 Refractive index 、 Enthalpy 、 Formamide
摘要: The thermophysical properties of binary mixtures formamide with 2-methoxyethanol and 2-ethoxyethanol have been investigated in this article. Densities, refractive index, ultrasonic velocity viscosity for the two viz. measured over entire composition range at 293, 303 313 K atmospheric pressure. excess molar volume, refraction deviation, Gibb's free energy activation viscous flow, isentropic compressibility, deviation viscosity, volume enthalpy computed using experimental data. These parameters correlated Redlich–Kister polynomial equation. results interpreted on basis strength intermolecular interaction occurring these mixtures. index were second-order partial a...
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