Ionic effects in self-propelled Pt-coated Janus swimmers

作者: Aidan Brown , Wilson Poon , None

DOI: 10.1039/C4SM00340C

关键词: Chemical engineeringPolystyreneIonic bondingBimetallic stripReaction ratePulmonary surfactantParticleInorganic chemistryColloidSalt (chemistry)Chemistry

摘要: Colloidal particles partially coated with platinum and dispersed in H2O2 solution are often used as model self-propelled colloids. Most current data suggest that neutral self-diffusiophoresis propels these particles. However, several studies have shown strong ionic effects this related systems, such a reduction of propulsion speed by salt. We investigate Pt-coated polystyrene colloids, find here the direction can be reversed addition an surfactant, although adding pH salts reduces speed, base NaOH has little effect. use data, well measured reaction rates, to argue against either or self-diffusiophoresis, instead particle's mechanism may fact bear close resemblance operative bimetallic swimmers.

参考文章(70)
Joseph Weiss, The Free Radical Mechanism in the Reactions of Hydrogen peroxide Advances in Catalysis. ,vol. 4, pp. 343- 365 ,(1952) , 10.1016/S0360-0564(08)60618-5
Henry V. Kehiaian, David R. Lide, CRC Handbook of Thermophysical and Thermochemical Data ,(1994)
Jérémie Palacci, Cécile Cottin-Bizonne, Christophe Ybert, Lydéric Bocquet, Sedimentation and effective temperature of active colloidal suspensions. Physical Review Letters. ,vol. 105, pp. 088304- ,(2010) , 10.1103/PHYSREVLETT.105.088304
F. Van Den Brink, W. Visscher, E. Barendrecht, Electrocatalysis of cathodic oxygen reduction by metal phthalocyanines Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. ,vol. 172, pp. 301- 325 ,(1984) , 10.1016/0022-0728(84)80194-1
Víctor Climent, Roberto Gómez, José M Orts, Juan M Feliu, None, Thermodynamic analysis of the temperature dependence of OH adsorption on Pt(111) and Pt(100) electrodes in acidic media in the absence of specific anion adsorption. Journal of Physical Chemistry B. ,vol. 110, pp. 11344- 11351 ,(2006) , 10.1021/JP054948X
C. Cottin-Bizonne, B. Cross, A. Steinberger, E. Charlaix, Boundary slip on smooth hydrophobic surfaces: intrinsic effects and possible artifacts. Physical Review Letters. ,vol. 94, pp. 056102- ,(2005) , 10.1103/PHYSREVLETT.94.056102
Howard A. Stone, Aravinthan D. T. Samuel, Propulsion of Microorganisms by Surface Distortions Physical Review Letters. ,vol. 77, pp. 4102- 4104 ,(1996) , 10.1103/PHYSREVLETT.77.4102
Manoj Manjare, Yuan Ting Wu, Bo Yang, Y.-P. Zhao, Hydrophobic catalytic Janus motors: Slip boundary condition and enhanced catalytic reaction rate Applied Physics Letters. ,vol. 104, pp. 054102- ,(2014) , 10.1063/1.4863952
Armand Ajdari, Lydéric Bocquet, Giant amplification of interfacially driven transport by hydrodynamic slip: diffusio-osmosis and beyond. Physical Review Letters. ,vol. 96, pp. 186102- ,(2006) , 10.1103/PHYSREVLETT.96.186102