ADSORPTION AND SURFACE REACTIONS OF H[SUB]2 S AND SO[SUB]2 ON CU(100) STUDIED BY ELECTRON ENERGY LOSS SPECTROSCOPY

作者: K. T. Leung , X. S. Zhang , D. A. Shirley

DOI: 10.1021/J100353A042

关键词: Inorganic chemistryCopperChemical reactionAnalytical chemistryChemistryAdsorptionElectron spectroscopyTransition metalElectron energy loss spectroscopySpectroscopyDissociation (chemistry)

摘要: The adsorption of H{sub 2}S and SO{sub 2} on Cu(100) was investigated by use electron energy loss spectroscopy as a function coverage, temperature, scattering angles. In particular, irreversible dissociation the formation sulfhydryl (SH) species at low immediate coverage were observed temperature. This followed molecular physiadsorption higher coverage. case Cu(100), decomposition 3} surface room temperature observed. A reaction involving preadsorbed with 2}s is discussed.

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